Synthesis of 6-, 7-and 8-membered cyclosiloxanes having multifunctional groups
Cyclosiloxanes having intramolecular donor atoms, a Si-Si bond, and vinyl groups were synthesized as useful precursors for ring-opening polymerization.1,1,3,3-Tetrakis(dimethylaminomethylphenyl)-5,5-dimethylcyclotrisiloxane was also synthesized and characterized by single crystal X-ray structural analysis, which shows strong coordination from N to Si in the solid state. (C) 2011 Elsevier B.V. All rights reserved.k
- Publisher
- ELSEVIER SCIENCE SA
- Issue Date
- 2011-07
- Language
- English
- Article Type
- Article
- Keywords
ELECTROCHEMICAL OXIDATION; CYCLIC POLYSILANES; DISILOXANE-1,3-DIOLS; ISOMERIZATION; BEHAVIOR
- Citation
JOURNAL OF ORGANOMETALLIC CHEMISTRY, v.696, no.14, pp.2754 - 2757
- ISSN
- 0022-328X
- Appears in Collection
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