DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Jaechul | ko |
dc.contributor.author | Chuah, Chong Yang | ko |
dc.contributor.author | Kim, Jaheon | ko |
dc.contributor.author | Kim, Youngsuk | ko |
dc.contributor.author | Ko, Nakeun | ko |
dc.contributor.author | Seo, Younggyu | ko |
dc.contributor.author | Kim, Kimoon | ko |
dc.contributor.author | Bae, Tae Hyun | ko |
dc.contributor.author | Lee, Eunsung | ko |
dc.date.accessioned | 2019-05-29T07:25:10Z | - |
dc.date.available | 2019-05-29T07:25:10Z | - |
dc.date.created | 2019-05-29 | - |
dc.date.created | 2019-05-29 | - |
dc.date.created | 2019-05-29 | - |
dc.date.created | 2019-05-29 | - |
dc.date.created | 2019-05-29 | - |
dc.date.issued | 2018-06 | - |
dc.identifier.citation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.57, no.26, pp.7869 - 7873 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10203/262311 | - |
dc.description.abstract | Separation of acetylene from carbon dioxide and ethylene is challenging in view of their similar sizes and physical properties. Metal-organic frameworks (MOFs) in general are strong candidates for these separations owing to the presence of functional pore surfaces that can selectively capture a specific target molecule. Here, we report a novel 3D microporous cationic framework named JCM-1. This structure possesses imidazolium functional groups on the pore surfaces and pyrazolate as a metal binding group, which is well known to form strong metal-to-ligand bonds. The selective sorption of acetylene over carbon dioxide and ethylene in JCM-1 was successfully demonstrated by equilibrium gas adsorption analysis as well as dynamic breakthrough measurement. Furthermore, its excellent hydrolytic stability makes the separation processes highly recyclable without a substantial loss in acetylene uptake capacity. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Separation of Acetylene from Carbon Dioxide and Ethylene by a Water-Stable Microporous Metal-Organic Framework with Aligned Imidazolium Groups inside the Channels | - |
dc.type | Article | - |
dc.identifier.wosid | 000435766800052 | - |
dc.identifier.scopusid | 2-s2.0-85047501653 | - |
dc.type.rims | ART | - |
dc.citation.volume | 57 | - |
dc.citation.issue | 26 | - |
dc.citation.beginningpage | 7869 | - |
dc.citation.endingpage | 7873 | - |
dc.citation.publicationname | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.identifier.doi | 10.1002/anie.201804442 | - |
dc.contributor.localauthor | Bae, Tae Hyun | - |
dc.contributor.nonIdAuthor | Lee, Jaechul | - |
dc.contributor.nonIdAuthor | Chuah, Chong Yang | - |
dc.contributor.nonIdAuthor | Kim, Jaheon | - |
dc.contributor.nonIdAuthor | Kim, Youngsuk | - |
dc.contributor.nonIdAuthor | Ko, Nakeun | - |
dc.contributor.nonIdAuthor | Seo, Younggyu | - |
dc.contributor.nonIdAuthor | Kim, Kimoon | - |
dc.contributor.nonIdAuthor | Lee, Eunsung | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | acetylene | - |
dc.subject.keywordAuthor | gas separation | - |
dc.subject.keywordAuthor | imidazolium | - |
dc.subject.keywordAuthor | ionic liquids | - |
dc.subject.keywordAuthor | metal-organic frameworks | - |
dc.subject.keywordPlus | N-HETEROCYCLIC CARBENE | - |
dc.subject.keywordPlus | POROUS COORDINATION POLYMERS | - |
dc.subject.keywordPlus | ENHANCED C2H2/CO2 SEPARATION | - |
dc.subject.keywordPlus | ROOM-TEMPERATURE | - |
dc.subject.keywordPlus | IONIC LIQUIDS | - |
dc.subject.keywordPlus | HYDROCARBON SEPARATIONS | - |
dc.subject.keywordPlus | SELECTIVE SEPARATION | - |
dc.subject.keywordPlus | GAS-ADSORPTION | - |
dc.subject.keywordPlus | CO2 CAPTURE | - |
dc.subject.keywordPlus | STORAGE | - |
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