New synthesis of 3-deoxypurine nucleosides using samarium(III) iodide complex
Regio- and stereoselective iodinative cleavage of 2',3'-anhydropurine nucleosides was achieved with samarium diiodide and ethyl bromoacetate to produce the corresponding 3'-iodopurine nucleosides, which were then converted to 3'-deoxypurine nucleosides including the natural product cordycepin. (C) 2003 Elsevier Ltd. All rights reserved.
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Issue Date
- 2003-10
- Language
- English
- Article Type
- Article
- Keywords
EFFICIENT SYNTHESIS; 2-ACYLOXYISOBUTYRYL HALIDES; ADENOSINE; 3' -DEOXYADENOSINE; CORDYCEPIN; ACID; RNA; DNA
- Citation
TETRAHEDRON LETTERS, v.44, no.43, pp.7941 - 7943
- ISSN
- 0040-4039
- Appears in Collection
- BS-Journal Papers(저널논문)
- Files in This Item
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