DC Field | Value | Language |
---|---|---|
dc.contributor.author | Liu, Fei | ko |
dc.contributor.author | Piao, Yunxian | ko |
dc.contributor.author | Choi, Ki-Seok | ko |
dc.contributor.author | Seo, Tae-Seok | ko |
dc.date.accessioned | 2013-03-11T15:26:33Z | - |
dc.date.available | 2013-03-11T15:26:33Z | - |
dc.date.created | 2012-03-07 | - |
dc.date.created | 2012-03-07 | - |
dc.date.issued | 2012-01 | - |
dc.identifier.citation | CARBON, v.50, no.1, pp.123 - 133 | - |
dc.identifier.issn | 0008-6223 | - |
dc.identifier.uri | http://hdl.handle.net/10203/99468 | - |
dc.description.abstract | We report a simple fabrication method for large-scale free-standing graphene-gold nanoparticle and graphene-single wall carbon nanotube composite films by using a centrifugal vacuum evaporation followed by a thermal reduction process. The homogeneous mixture of a graphene oxide (GO) suspension with gold nanoparticle (Au NP) or single wall carbon nanotube (SWCNT) is self-assembled at the air/liquid interface, resulting in the multilayered GO-Au NP and GO-SWCNT composite films. The cross-sectional image reveals that the graphene layers are orderly stacked in the reduced GO-Au NP film, while the reduced GO-SWCNT film shows a randomly packed morphology due to the dominant pi-pi interaction between the side wall of SWCNTs and the GO surfaces. In particular, the reduced GO-Au NP film shows an increased electrode kinetics and cyclic voltammetric response in proportion to the amount of Au NPs, and 3-fold enhancement of anodic peak current was observed compared with that of the reduced GO films. We employed the reduced GO-Au NP film as a matrix to immobilize tyrosinase enzyme for phenol detection, and the phenol-induced electrochemical catalytic reaction can be monitored with 3-fold higher sensitivity than the reduced GO film, demonstrating great potential of graphene composite as an electrochemical enzyme biosensor for environmental pollutant screening. (C) 2011 Elsevier Ltd. All rights reserved. | - |
dc.language | English | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.subject | CARBON NANOTUBES | - |
dc.subject | GOLD NANOPARTICLES | - |
dc.subject | ASSISTED DISPERSION | - |
dc.subject | OXIDE | - |
dc.subject | NANOCOMPOSITES | - |
dc.subject | REDUCTION | - |
dc.subject | SHEETS | - |
dc.subject | SUPERCAPACITORS | - |
dc.subject | CATALYSTS | - |
dc.subject | ARRAYS | - |
dc.title | Fabrication of free-standing graphene composite films as electrochemical biosensors | - |
dc.type | Article | - |
dc.identifier.wosid | 000296548800013 | - |
dc.identifier.scopusid | 2-s2.0-80053603889 | - |
dc.type.rims | ART | - |
dc.citation.volume | 50 | - |
dc.citation.issue | 1 | - |
dc.citation.beginningpage | 123 | - |
dc.citation.endingpage | 133 | - |
dc.citation.publicationname | CARBON | - |
dc.identifier.doi | 10.1016/j.carbon.2011.07.061 | - |
dc.contributor.localauthor | Seo, Tae-Seok | - |
dc.contributor.nonIdAuthor | Piao, Yunxian | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | CARBON NANOTUBES | - |
dc.subject.keywordPlus | GOLD NANOPARTICLES | - |
dc.subject.keywordPlus | ASSISTED DISPERSION | - |
dc.subject.keywordPlus | OXIDE | - |
dc.subject.keywordPlus | NANOCOMPOSITES | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.subject.keywordPlus | SHEETS | - |
dc.subject.keywordPlus | SUPERCAPACITORS | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | ARRAYS | - |
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