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College of Engineering(공과대학)Dept. of Materials Science and Engineering(신소재공학과)MS-Journal Papers(저널논문)

Chemical diffusion of electroactive species in ionic compounds: a focus on chemical equilibrium constraint

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dc.contributor.authorLee, Sung-Jaiko
dc.contributor.authorPyun, Su Ilko
dc.contributor.authorShin, Heon-Cheolko
dc.date.accessioned2013-03-09T14:25:49Z-
dc.date.available2013-03-09T14:25:49Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2009-
dc.identifier.citationJOURNAL OF SOLID STATE ELECTROCHEMISTRY, v.13, no.6, pp.829 - 836-
dc.identifier.issn1432-8488-
dc.identifier.urihttp://hdl.handle.net/10203/96595-
dc.description.abstractThis work aims at considering the theoretical basis of chemical diffusion of electroactive species in ionic compounds, in particular from the perspective of the chemical equilibrium constraint. For this purpose, first a variety of descriptions on diffusivity are briefly summarised from the viewpoint of driving forces. Then, the equations to stand for the chemical diffusion behaviour are theoretically derived with and without the chemical equilibrium constraint. Finally, the two different situations above are critically compared to explore the origin of chemical diffusion in ionic compounds.-
dc.languageEnglish-
dc.publisherSpringer-
dc.subjectELECTROCHEMICAL LITHIUM INTERCALATION-
dc.subjectINTERNAL DEFECT REACTIONS-
dc.subjectMASS-TRANSPORT-
dc.subjectCONSERVATIVE ENSEMBLES-
dc.subjectAMBIPOLAR DIFFUSION-
dc.subjectNANOPOROUS TIO2-
dc.subjectFILM ELECTRODE-
dc.subjectSILICON-
dc.subjectCONDUCTIVITY-
dc.subjectCRYSTALS-
dc.titleChemical diffusion of electroactive species in ionic compounds: a focus on chemical equilibrium constraint-
dc.typeArticle-
dc.identifier.wosid000264485700002-
dc.identifier.scopusid2-s2.0-62949216965-
dc.type.rimsART-
dc.citation.volume13-
dc.citation.issue6-
dc.citation.beginningpage829-
dc.citation.endingpage836-
dc.citation.publicationnameJOURNAL OF SOLID STATE ELECTROCHEMISTRY-
dc.identifier.doi10.1007/s10008-008-0617-0-
dc.contributor.nonIdAuthorShin, Heon-Cheol-
dc.type.journalArticleReview-
dc.subject.keywordAuthorChemical diffusion-
dc.subject.keywordAuthorIonic compound-
dc.subject.keywordAuthorChemical diffusivity-
dc.subject.keywordAuthorComponent diffusivity-
dc.subject.keywordAuthorChemical equilibrium constraint-
dc.subject.keywordPlusELECTROCHEMICAL LITHIUM INTERCALATION-
dc.subject.keywordPlusINTERNAL DEFECT REACTIONS-
dc.subject.keywordPlusMASS-TRANSPORT-
dc.subject.keywordPlusCONSERVATIVE ENSEMBLES-
dc.subject.keywordPlusAMBIPOLAR DIFFUSION-
dc.subject.keywordPlusNANOPOROUS TIO2-
dc.subject.keywordPlusFILM ELECTRODE-
dc.subject.keywordPlusSILICON-
dc.subject.keywordPlusCONDUCTIVITY-
dc.subject.keywordPlusCRYSTALS-
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