The fabrication of single and multimode waveguides and optical characteristics were investigated. The singlemode waveguide was fabricated by a laser direct writing technique and a multimode waveguide was produced by means of a direct UV patterning technique using organic-inorganic hybrid materials. The fabrication of waveguide channels with these techniques are of interest for simple processes. The resulting single and multimode waveguides exhibited a near rectangular shape and low optical loss. The average propagation losses of these waveguides were 0.07 dB/cm (at 850 nm) and 0.3 dB/cm (at 1310nm), respectively.