Low valent phosphorus in the molecular anions [P5Se12](5-) and beta-[P6Se12](4-): phase change behavior and near infrared second harmonic generation

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The caesium salts of the novel molecular anions [P5Se12](5-) and [P6Se12](4-) are phase change materials and exhibit near infrared, non-linear optical second harmonic generation; [P5Se12](5-) is a coordination complex with an octahedral P3+ center chelated by two [P2Se6](4-) ligands whereas [P6Se12](4-) features a [P-2](4+) dimer chelated by two [P2Se6](4-) ligands.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2007
Language
English
Article Type
Article
Keywords

CRYSTAL-STRUCTURE; RB; SELENOPHOSPHATES; FRAGMENTS; SN2P2S6; CENTERS; STORAGE; CS

Citation

CHEMICAL COMMUNICATIONS, pp.4998 - 5000

ISSN
1359-7345
DOI
10.1039/b714301j
URI
http://hdl.handle.net/10203/93217
Appears in Collection
NT-Journal Papers(저널논문)
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