Low valent phosphorus in the molecular anions [P5Se12](5-) and beta-[P6Se12](4-): phase change behavior and near infrared second harmonic generation

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dc.contributor.authorChung, Inko
dc.contributor.authorJang, Joon I.ko
dc.contributor.authorGave, Matthew A.ko
dc.contributor.authorWeliky, David P.ko
dc.contributor.authorKanatzidis, Mercouri G.ko
dc.date.accessioned2013-03-08T14:10:47Z-
dc.date.available2013-03-08T14:10:47Z-
dc.date.created2013-02-19-
dc.date.created2013-02-19-
dc.date.issued2007-
dc.identifier.citationCHEMICAL COMMUNICATIONS, pp.4998 - 5000-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10203/93217-
dc.description.abstractThe caesium salts of the novel molecular anions [P5Se12](5-) and [P6Se12](4-) are phase change materials and exhibit near infrared, non-linear optical second harmonic generation; [P5Se12](5-) is a coordination complex with an octahedral P3+ center chelated by two [P2Se6](4-) ligands whereas [P6Se12](4-) features a [P-2](4+) dimer chelated by two [P2Se6](4-) ligands.-
dc.languageEnglish-
dc.publisherROYAL SOC CHEMISTRY-
dc.subjectCRYSTAL-STRUCTURE-
dc.subjectRB-
dc.subjectSELENOPHOSPHATES-
dc.subjectFRAGMENTS-
dc.subjectSN2P2S6-
dc.subjectCENTERS-
dc.subjectSTORAGE-
dc.subjectCS-
dc.titleLow valent phosphorus in the molecular anions [P5Se12](5-) and beta-[P6Se12](4-): phase change behavior and near infrared second harmonic generation-
dc.typeArticle-
dc.identifier.wosid000251336600004-
dc.identifier.scopusid2-s2.0-36649031837-
dc.type.rimsART-
dc.citation.beginningpage4998-
dc.citation.endingpage5000-
dc.citation.publicationnameCHEMICAL COMMUNICATIONS-
dc.identifier.doi10.1039/b714301j-
dc.contributor.localauthorChung, In-
dc.contributor.nonIdAuthorJang, Joon I.-
dc.contributor.nonIdAuthorGave, Matthew A.-
dc.contributor.nonIdAuthorWeliky, David P.-
dc.contributor.nonIdAuthorKanatzidis, Mercouri G.-
dc.type.journalArticleArticle-
dc.subject.keywordPlusCRYSTAL-STRUCTURE-
dc.subject.keywordPlusRB-
dc.subject.keywordPlusSELENOPHOSPHATES-
dc.subject.keywordPlusFRAGMENTS-
dc.subject.keywordPlusSN2P2S6-
dc.subject.keywordPlusCENTERS-
dc.subject.keywordPlusSTORAGE-
dc.subject.keywordPlusCS-
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