Preorganization in highly enantioselective diaza-Cope rearrangement reaction
Crystal structure and activation entropy data indicate that H-bond directed diaza-Cope rearrangement of chiral diimines takes place with a high degree of preorganization. CD spectroscopy and HPLC data show that there is inversion of stereochemistry for the reaction with excellent enantioselectivity.
- Publisher
- American Chemical Society
- Issue Date
- 2005-11
- Language
- English
- Article Type
- Article
- Citation
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.127, no.47, pp.16370 - 16371
- ISSN
- 0002-7863
- Appears in Collection
- CH-Journal Papers(저널논문)
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- There are no files associated with this item.
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