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College of Engineering(공과대학)Dept. of Chemical and Biomolecular Engineering(생명화학공학과)CBE-Journal Papers(저널논문)

1,3-dipolar cycloaddition of azides with electron-deficient alkynes under mild condition in water

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dc.contributor.authorLi, ZMko
dc.contributor.authorSEO, TAE SEOKko
dc.contributor.authorJu, JYko
dc.date.accessioned2009-05-06T02:18:44Z-
dc.date.available2009-05-06T02:18:44Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2004-04-
dc.identifier.citationTETRAHEDRON LETTERS, v.45, no.15, pp.3143 - 3146-
dc.identifier.issn0040-4039-
dc.identifier.urihttp://hdl.handle.net/10203/8846-
dc.description.abstractWe report a simple synthetic protocol for the 1,3-dipolar cycloaddition of azides with electron-deficient alkynes. Alkyne with at least one neighboring electron-withdrawing group proceeds with the cycloaddition successfully without any catalysts at room temperature in water. Under this simple condition, we evaluated a series of small molecule model reactions and then coupled an azido-DNA molecule with electron-deficient alkynes for the formation of [1,2,3]-triazole heterocycle, providing a potential method for introducing functional groups to DNA under biological conditions. (C) 2004 Elsevier Ltd. All rights reserved.-
dc.description.sponsorshipThe National Scinece Foundation (sensing and Imaging Initiative Grant 0097793), and a Center of Excellence in Genomic Science Grant (P50 HG002806) from the National Institutes of Healthen
dc.languageEnglish-
dc.language.isoen_USen
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.subjectTERMINAL ALKYNES-
dc.subjectCLICK CHEMISTRY-
dc.subjectCUCURBITURIL-
dc.subjectCATALYSIS-
dc.title1,3-dipolar cycloaddition of azides with electron-deficient alkynes under mild condition in water-
dc.typeArticle-
dc.identifier.wosid000220554500031-
dc.identifier.scopusid2-s2.0-1642281920-
dc.type.rimsART-
dc.citation.volume45-
dc.citation.issue15-
dc.citation.beginningpage3143-
dc.citation.endingpage3146-
dc.citation.publicationnameTETRAHEDRON LETTERS-
dc.identifier.doi10.1016/j.tetlet.2004.02.089-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorSEO, TAE SEOK-
dc.contributor.nonIdAuthorLi, ZM-
dc.contributor.nonIdAuthorJu, JY-
dc.type.journalArticleArticle-
dc.subject.keywordAuthor1,3-dipolar cycloaddition-
dc.subject.keywordAuthorelectron-deficient alkynes-
dc.subject.keywordAuthor5 &apos-
dc.subject.keywordAuthor-azido DNA-
dc.subject.keywordPlusTERMINAL ALKYNES-
dc.subject.keywordPlusCLICK CHEMISTRY-
dc.subject.keywordPlusCUCURBITURIL-
dc.subject.keywordPlusCATALYSIS-
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