Electrochemical lithiation reactions of Cu6Sn5 and their reaction products

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dc.contributor.authorChoi, Wko
dc.contributor.authorLee, JeongYongko
dc.contributor.authorLim, HSko
dc.date.accessioned2013-03-06T04:02:27Z-
dc.date.available2013-03-06T04:02:27Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2004-08-
dc.identifier.citationELECTROCHEMISTRY COMMUNICATIONS, v.6, pp.816 - 820-
dc.identifier.issn1388-2481-
dc.identifier.urihttp://hdl.handle.net/10203/85748-
dc.description.abstractElectrochemical lithiation reactions of a thin-film Cu6Sn5 alloy electrode were studied in an organic carbonate electrolyte containing LiPF6 salt using conventional charge-discharge techniques and analysing the reaction products by transmission electron microscopy (TEM). A partially lithiated phase, LixCu6Sn5, (where x < 3), that appears to be a solid solution of Li in the basic crystal structure of Cu6Sn5 was identified by TEM in a Cu6Sn5-alloy electrode discharged at 0.5 V. At a further cathodic potential of 0.3 V the formation of Li2CuSn was observed in agreement with earlier reports. At the potential close to that of the Li-metal plating (similar to0.01 V discharge cut-off) Li7Sn2 phase was identified as the main composition without observation of a further lithiated phase beyond Li7Sn2. (C) 2004 Elsevier B.V. All rights reserved.-
dc.languageEnglish-
dc.publisherELSEVIER SCIENCE INC-
dc.subjectSITU X-RAY-
dc.subjectLITHIUM BATTERIES-
dc.subjectION BATTERIES-
dc.subjectANODES-
dc.subjectELECTRODES-
dc.subjectSTORAGE-
dc.subjectPOWDERS-
dc.subjectSILICON-
dc.subjectSYSTEM-
dc.subjectSN-
dc.titleElectrochemical lithiation reactions of Cu6Sn5 and their reaction products-
dc.typeArticle-
dc.identifier.wosid000222894600015-
dc.identifier.scopusid2-s2.0-3242801312-
dc.type.rimsART-
dc.citation.volume6-
dc.citation.beginningpage816-
dc.citation.endingpage820-
dc.citation.publicationnameELECTROCHEMISTRY COMMUNICATIONS-
dc.contributor.localauthorLee, JeongYong-
dc.contributor.nonIdAuthorChoi, W-
dc.contributor.nonIdAuthorLim, HS-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorLi-Cu-Sn alloy-
dc.subject.keywordAuthoralloy anode-
dc.subject.keywordAuthorintermetallic compound-
dc.subject.keywordAuthortransmission electron microscopy-
dc.subject.keywordPlusSITU X-RAY-
dc.subject.keywordPlusLITHIUM BATTERIES-
dc.subject.keywordPlusION BATTERIES-
dc.subject.keywordPlusANODES-
dc.subject.keywordPlusELECTRODES-
dc.subject.keywordPlusSTORAGE-
dc.subject.keywordPlusPOWDERS-
dc.subject.keywordPlusSILICON-
dc.subject.keywordPlusSYSTEM-
dc.subject.keywordPlusSN-
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