DC Field | Value | Language |
---|---|---|
dc.contributor.author | Choi, YS | ko |
dc.contributor.author | Ham, HT | ko |
dc.contributor.author | Chung, In Jae | ko |
dc.date.accessioned | 2013-03-03T18:27:36Z | - |
dc.date.available | 2013-03-03T18:27:36Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2003-12 | - |
dc.identifier.citation | POLYMER, v.44, no.26, pp.8147 - 8154 | - |
dc.identifier.issn | 0032-3861 | - |
dc.identifier.uri | http://hdl.handle.net/10203/79898 | - |
dc.description.abstract | Polymer/silicate nanocomposites were synthesized using potassium persulfate (KPS) in the presence of silicate and 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) without exterior redox co-catalysts at a room temperature. A mechanism for the room temperature polymerization in the presence of silicate was suggested: AMPS attached on the surface of silicate layers would oxidize Fe+2 in silicate lattice to become Fe+3 and the Fe+3 would decompose KPS to form radicals like redox co-catalysts. Poly (acrylonitrile) (PAN)/silicate nanocomposite showed an exfoliated structure, but poly (methyl methacrylate) (PMMA)/silicate nanocomposite showed an intercalated structure. Polymers recovered from the nanocomposites synthesized at a room temperature had high isotactic configurations compared to bulk polymers. The dipole-dipole interaction between monomers and silicate surface might make the lamella of monomers to form on the silicate layer surface and produced polymers with more isotactic configurations. PAN/silicate nanocomposite showed two glass transition temperatures at 113 and 151 degreesC. The lower temperature might be related to the molecules with low molecular weight. PMMA/silicate nanocomposite had a storage modulus of 4.47 x 10(9) Pa at 40 degreesC. (C) 2003 Elsevier Ltd. All rights reserved. | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCI LTD | - |
dc.subject | X-RAY-SCATTERING | - |
dc.subject | EMULSION POLYMERIZATION | - |
dc.subject | MMT NANOCOMPOSITES | - |
dc.subject | POLYACRYLONITRILE | - |
dc.subject | CATALYSTS | - |
dc.subject | MICELLES | - |
dc.subject | MINERALS | - |
dc.subject | FIBERS | - |
dc.title | Polymer/silicate nanocomposites synthesized with potassium persulfate at room temperature: polymerization mechanism, characterization, and mechanical properties of the nanocomposites | - |
dc.type | Article | - |
dc.identifier.wosid | 000186949800042 | - |
dc.type.rims | ART | - |
dc.citation.volume | 44 | - |
dc.citation.issue | 26 | - |
dc.citation.beginningpage | 8147 | - |
dc.citation.endingpage | 8154 | - |
dc.citation.publicationname | POLYMER | - |
dc.identifier.doi | 10.1016/j.polymer.2003.10.041 | - |
dc.contributor.nonIdAuthor | Choi, YS | - |
dc.contributor.nonIdAuthor | Ham, HT | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | silicate | - |
dc.subject.keywordAuthor | nanocomposites | - |
dc.subject.keywordAuthor | room temperature polymerization | - |
dc.subject.keywordPlus | X-RAY-SCATTERING | - |
dc.subject.keywordPlus | EMULSION POLYMERIZATION | - |
dc.subject.keywordPlus | MMT NANOCOMPOSITES | - |
dc.subject.keywordPlus | POLYACRYLONITRILE | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | MICELLES | - |
dc.subject.keywordPlus | MINERALS | - |
dc.subject.keywordPlus | FIBERS | - |
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