DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jung, Sung-Ouk | ko |
dc.contributor.author | Jung, Myung-Sup | ko |
dc.contributor.author | Choi, Tae-Lim | ko |
dc.contributor.author | Huhl, Nam | ko |
dc.contributor.author | Ko, Christopher | ko |
dc.contributor.author | Jung, HeeTae | ko |
dc.date.accessioned | 2008-09-23T05:13:43Z | - |
dc.date.available | 2008-09-23T05:13:43Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2008 | - |
dc.identifier.citation | POLYMERS FOR ADVANCED TECHNOLOGIES, v.19, no.3, pp.237 - 243 | - |
dc.identifier.issn | 1042-7147 | - |
dc.identifier.uri | http://hdl.handle.net/10203/7404 | - |
dc.description.abstract | To achieve easy spin coating and enhanced efficiency in the photolithographic process for the direct photochemical modification of surface, we incorporated photoacid generator WAG) into polymer backbone. Bis-(4-hydroxy-phenyl)-(4-methoxy-3,5-dimethyl-phenyl)-sulfonium chloride was synthesized as a monomer, and was polymerized with sebacoyl chloride and terephthaloyl chloride. The resulting polymeric PAG in chloride salt form was converted to the p-toluenesulfonate and 1-naphthol-5-sulfonate forms with ion-exchange reactions. By the photolithographic process with the polymeric PAG, the protecting groups of the linker molecules self-assembled onto a glass plate were micropatterned to produce an amine pattern for the microarray of oligonucleotides. The acids generated from the polymeric PAG effectively deprotect the acid-labile protecting groups of the linker molecules through a chemical amplification process in the exposed region. After the treatment of the patterned amino groups with a fluorescent dye, the pattern profiles were observed with a fluorescence scanner. The fluorescence image reveals a well-defined pattern at a micro level, which clearly indicates that the polymeric PAGs have a great potential in photochemical surface modification for the microarray of oligonucleotides. Copyright (c) 2007 John Wiley & Sons, Ltd. | - |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | JOHN WILEY & SONS LTD | - |
dc.subject | DNA | - |
dc.subject | ATTACHMENT | - |
dc.subject | CHEMISTRY | - |
dc.title | Polymeric photoacid generators for direct photochemical modification of surface | - |
dc.type | Article | - |
dc.identifier.wosid | 000255008500010 | - |
dc.identifier.scopusid | 2-s2.0-42149114615 | - |
dc.type.rims | ART | - |
dc.citation.volume | 19 | - |
dc.citation.issue | 3 | - |
dc.citation.beginningpage | 237 | - |
dc.citation.endingpage | 243 | - |
dc.citation.publicationname | POLYMERS FOR ADVANCED TECHNOLOGIES | - |
dc.identifier.doi | 10.1002/pat.1005 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Jung, HeeTae | - |
dc.contributor.nonIdAuthor | Jung, Sung-Ouk | - |
dc.contributor.nonIdAuthor | Jung, Myung-Sup | - |
dc.contributor.nonIdAuthor | Choi, Tae-Lim | - |
dc.contributor.nonIdAuthor | Huhl, Nam | - |
dc.contributor.nonIdAuthor | Ko, Christopher | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | photolithography | - |
dc.subject.keywordAuthor | photoresist | - |
dc.subject.keywordAuthor | photoacid generator | - |
dc.subject.keywordAuthor | surface modification | - |
dc.subject.keywordPlus | DNA | - |
dc.subject.keywordPlus | ATTACHMENT | - |
dc.subject.keywordPlus | CHEMISTRY | - |
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