Synthesis of ketones with alkyl phosphonates and nitriles as acyl cation equivalent: Application of dephosphonylation reaction of beta-functionalized phosphonate with hydride
The preparation of several alpha-substituted ketones is performed in a one-pot procedure with alkyl phosphonates and aromatic nitriles by subsequent treatment of LiAlH4. A new method for nitriles used as an acyl cation equivalent is described.
- Publisher
- Taylor & Francis Inc
- Issue Date
- 1997
- Language
- English
- Article Type
- Article
- Keywords
ONE-POT SYNTHESIS
- Citation
SYNTHETIC COMMUNICATIONS, v.27, no.19, pp.3333 - 3339
- ISSN
- 0039-7911
- Appears in Collection
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