First Example of 1,1-Bimetalloalkenes of Tellurium and zirconium: Application for Stereoselective Preparation of (Z)-$\alpha$-Organotelluro-$\alpha$,$\beta$-unsaturated Carbonyl Compounds

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Hydrozirconation of acetylenic tellurides 1 affords the first examples of 1,1-bimetalloalkenes of tellurium and zirconium 2. Intermediates 2 are reacted with acyl halides to obtain (Z)-alpha-organotelluro- alpha,beta-unsaturated carbonyl compounds 4 via Zr-Cu transmetallation. Copyright (C) 1996 Elsevier Science Ltd
Publisher
Pergamon-Elsevier Science Ltd
Issue Date
1996
Language
English
Article Type
Article
Keywords

PLANAR-TETRACOORDINATE CARBON; TRANSITION-METAL CATALYSIS; HYDROZIRCONATION-TRANSMETALATION; STEREOSPECIFIC SYNTHESIS; VINYLIC TELLURIDES; BOND FORMATION; HALIDES; REACTIVITY; ROUTE; 1,1-DIMETALLOALKENES

Citation

TETRAHEDRON LETTERS, v.37, no.42, pp.7537 - 7540

ISSN
0040-4039
URI
http://hdl.handle.net/10203/72339
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