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Reactions of Phosphites with Nitroalkene Derivatives: Syntheses of $\Beta$-Keto Phosphonates and $\alpha$-Cyanoalkylphosphonates

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dc.contributor.authorD.Y. Kimko
dc.contributor.authorOh, Dong Youngko
dc.date.accessioned2013-02-27T22:51:23Z-
dc.date.available2013-02-27T22:51:23Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued1997-
dc.identifier.citationBULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.18, no.9, pp.994 - 998-
dc.identifier.issn0253-2964-
dc.identifier.urihttp://hdl.handle.net/10203/71304-
dc.description.abstractThe addition of phosphite derivatives 1 to nitroalkenes 2 afforded alpha-phosphoryl nitronates which, on treatment MCPBA, were converted beta-keto phosphonates 3. A versatile reaction conditions to generate alpha-phosphoryl nitronates were examined. alpha-Cyanoalkylphosphonates 6 were prepared from the diethyl trimethylsilyl phosphite (DTSP) 1c with nitroalkenes 2 and followed by reduction.-
dc.languageEnglish-
dc.publisherKorean Chemical Soc-
dc.subjectENAMINE PHOSPHONATES-
dc.subjectORGANIC-SYNTHESIS-
dc.subjectVINYL PHOSPHATES-
dc.subjectFACILE SYNTHESIS-
dc.subjectCARBOMYCIN-B-
dc.subjectREAGENTS-
dc.subjectACID-
dc.subjectKETOPHOSPHONATES-
dc.subjectOLEFINS-
dc.subjectESTERS-
dc.titleReactions of Phosphites with Nitroalkene Derivatives: Syntheses of $\Beta$-Keto Phosphonates and $\alpha$-Cyanoalkylphosphonates-
dc.typeArticle-
dc.identifier.wosidA1997YB01800017-
dc.identifier.scopusid2-s2.0-0642331636-
dc.type.rimsART-
dc.citation.volume18-
dc.citation.issue9-
dc.citation.beginningpage994-
dc.citation.endingpage998-
dc.citation.publicationnameBULLETIN OF THE KOREAN CHEMICAL SOCIETY-
dc.contributor.nonIdAuthorD.Y. Kim-
dc.type.journalArticleArticle-
dc.subject.keywordPlusENAMINE PHOSPHONATES-
dc.subject.keywordPlusORGANIC-SYNTHESIS-
dc.subject.keywordPlusVINYL PHOSPHATES-
dc.subject.keywordPlusFACILE SYNTHESIS-
dc.subject.keywordPlusCARBOMYCIN-B-
dc.subject.keywordPlusREAGENTS-
dc.subject.keywordPlusACID-
dc.subject.keywordPlusKETOPHOSPHONATES-
dc.subject.keywordPlusOLEFINS-
dc.subject.keywordPlusESTERS-
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