Sintering behavior of cadmium-doped Pb(Ni1/3Nb2/3)O-3-PbZrO3-PbTiO3 ceramics

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Substituting Cd2+ ions into the A and B sites in a Pb(Ni1/3Nb2/3)O-3-PbZrO3-PbTiO3 (PNN-PZ-PT) ternary perovskite material made it possible to determine the effects of the Cd2+ ion substitution site on sintering behavior, The substitution site of the Cd2+ ion was identified by using X-ray photoelectron spectroscopy spectra. Although Cd2+ ions mere substituted into the A and B sites in PNN-PZ-PT, the Cd2+ ions preferred the A site over the B site. When Cd2+ ions replaced Pb2+ ions, a weight gain mas observed during sintering, On the other hand, replacing Ni2+ ions with Cd2+ ions promoted weight loss, Those weight changes indicated that Cd2+ ions change the bonding strength between the B-site cations and the oxygen of the octahedron in a perovskite structure, Density was influenced by the Cd2+ : ion substitution site, and the A-site-doped compositions had higher densities than the B-site-doped compositions.
Publisher
AMER CERAMIC SOC
Issue Date
1997-06
Language
English
Article Type
Article
Keywords

PIEZOELECTRIC PROPERTIES; PZT CERAMICS; PB(NI1/3NB2/3)O3-PBTIO3-PBZRO3 CERAMICS; DENSIFICATION; TEMPERATURE; ATMOSPHERE; OXIDE; PBO

Citation

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, v.80, no.6, pp.1523 - 1534

ISSN
0002-7820
URI
http://hdl.handle.net/10203/71075
Appears in Collection
MS-Journal Papers(저널논문)
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