PHOTOHYDRATION REACTION OF 1-(P-NITROPHENYL)-5,5-DIMETHYL-1,3-HEXADIYNE
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | eun kyung baek | ko |
| dc.contributor.author | sang chul shim | ko |
| dc.date.accessioned | 2013-02-27T19:12:29Z | - |
| dc.date.available | 2013-02-27T19:12:29Z | - |
| dc.date.created | 2012-02-06 | - |
| dc.date.created | 2012-02-06 | - |
| dc.date.issued | 1995 | - |
| dc.identifier.citation | JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, v.8, no.11, pp.699 - 705 | - |
| dc.identifier.issn | 0894-3230 | - |
| dc.identifier.uri | http://hdl.handle.net/10203/70309 | - |
| dc.description.abstract | Irradiation of 1-(p-nitrophenyl)-5,5-dimethyl-1,3-hexadiyne (NDHD) in aqueous sulfuric acid yields conjugated allenyl ketones (1 and 2) and beta-dicarbonyl compounds (3 and 4). The products 1 and 2 are primary photoproducts while 3 and 4 are secondary products formed by thermal hydration of the primary photoproducts showing the maximum quantum yield at H-0 = -1.0. A mechanism involving a synchronous addition of hydronium ion (H3O+) to a triplet state of NDHD is proposed. | - |
| dc.language | English | - |
| dc.publisher | JOHN WILEY & SONS LTD | - |
| dc.subject | AROMATIC ALKENES | - |
| dc.title | PHOTOHYDRATION REACTION OF 1-(P-NITROPHENYL)-5,5-DIMETHYL-1,3-HEXADIYNE | - |
| dc.type | Article | - |
| dc.identifier.wosid | A1995TJ05000001 | - |
| dc.type.rims | ART | - |
| dc.citation.volume | 8 | - |
| dc.citation.issue | 11 | - |
| dc.citation.beginningpage | 699 | - |
| dc.citation.endingpage | 705 | - |
| dc.citation.publicationname | JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | - |
| dc.identifier.doi | 10.1002/poc.610081102 | - |
| dc.contributor.nonIdAuthor | eun kyung baek | - |
| dc.type.journalArticle | Article | - |
| dc.subject.keywordPlus | AROMATIC ALKENES | - |
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