Thermal and electrochemical characteristics of plasticized polymer electrolytes based on poly(acrylonitrile-co-methyl methacrylate)

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The thermal and electrochemical characteristics of plasticized polymer electrolytes composed of poly(acrylonitrile-co-methyl methacrylate) [P(AN-co-MMA)], a plasticizer [a mixture of ethylene carbonate and propylene carbonate], and LiCF3SO3 were investigated. The incorporation of a MMA unit into the matrix polymer was effective for an increase in the compatibility between the matrix polymer and the plasticizer. The comparative investigation of the interfacial resistance of the Li/polymer electrolyte/Li cell for the PAN-based and the P(AN-ca-MMA)-based polymer electrolytes showed that the MMA unit could improve the stability of the polymer electrolyte toward the Li electrode, which is probably due to the enhanced adhesion of the polymer electrolyte to the Li electrode.
Publisher
SPRINGER VERLAG
Issue Date
1998-12
Language
English
Article Type
Article
Keywords

POLYACRYLONITRILE-BASED ELECTROLYTES; HYBRID FILMS; BATTERIES

Citation

JOURNAL OF SOLID STATE ELECTROCHEMISTRY, v.3, no.1, pp.1 - 6

ISSN
1432-8488
URI
http://hdl.handle.net/10203/69139
Appears in Collection
CBE-Journal Papers(저널논문)
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