DC Field | Value | Language |
---|---|---|
dc.contributor.author | CHUNG, Moon-Jo | ko |
dc.contributor.author | PARK, Kun-You | ko |
dc.contributor.author | LEE, Byung-Gwon | ko |
dc.contributor.author | Ihm, Son-Ki | ko |
dc.date.accessioned | 2008-05-08T06:15:12Z | - |
dc.date.available | 2008-05-08T06:15:12Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 1993-07 | - |
dc.identifier.citation | KOREAN JOURNAL OF CHEMICAL ENGINEERING, v.10, no.3, pp.188 - 190 | - |
dc.identifier.issn | 0256-1115 | - |
dc.identifier.uri | http://hdl.handle.net/10203/4447 | - |
dc.description.abstract | The reaction mechanism for the methylformate formation on Cu/ZnO catalysts from methanol and CO was investigated by the labeling study with C-13 methanol. It was found that methylformate could be formed through two parallel reaction routes, i.e., methanol-formaldehyde reaction and carbonylation of methanol depending upon the catalyst composition as well as the reaction conditions. The major reaction route on the high ZnO-content catalyst (Cu/ZnO=30/70) was found to be the methanol-formaldehyde reaction, and changed to the carbonylation reaction with the increase of CO partial pressure. On the other hand, the major reaction route on the high Cu-content catalyst (Cu/ZnO=80/20) remained as methanol-formaldehyde reaction even under the high CO pressure. | - |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | KOREAN INSTITUTE CHEMICAL ENGINEERS | - |
dc.title | METHYLFORMATE FORMATION FROM METHANOL AND CO ON CU/ZNO CATALYSTS | - |
dc.type | Article | - |
dc.identifier.wosid | A1993MJ96700008 | - |
dc.identifier.scopusid | 2-s2.0-51649139804 | - |
dc.type.rims | ART | - |
dc.citation.volume | 10 | - |
dc.citation.issue | 3 | - |
dc.citation.beginningpage | 188 | - |
dc.citation.endingpage | 190 | - |
dc.citation.publicationname | KOREAN JOURNAL OF CHEMICAL ENGINEERING | - |
dc.identifier.doi | 10.1007/BF02705142 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Ihm, Son-Ki | - |
dc.contributor.nonIdAuthor | CHUNG, Moon-Jo | - |
dc.contributor.nonIdAuthor | PARK, Kun-You | - |
dc.contributor.nonIdAuthor | LEE, Byung-Gwon | - |
dc.type.journalArticle | Note | - |
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