DC Field | Value | Language |
---|---|---|
dc.contributor.author | Hussain, M | ko |
dc.contributor.author | Song, SK | ko |
dc.contributor.author | Lee, JH | ko |
dc.contributor.author | Ihm, Son Ki | ko |
dc.date.accessioned | 2008-04-10T03:28:07Z | - |
dc.date.available | 2008-04-10T03:28:07Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2006-01 | - |
dc.identifier.citation | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, v.45, no.2, pp.536 - 543 | - |
dc.identifier.issn | 0888-5885 | - |
dc.identifier.uri | http://hdl.handle.net/10203/3767 | - |
dc.description.abstract | The potential of two different mesoporous materials, MCM-41- and MCM-48-supported sulfided CoMo bimetallic catalysts, for hydrodesulfurization (HDS) of thiophene at specific conditions was explored to investigate the effect of channel connectivity on HDS activity. The hydrothermal stability of MCM-41 and MCM-48 was improved remarkably by a post-salt treatment technique. Aluminum incorporation to mesoporous material frameworks improved acidity and hydrothermal stability. Mesoporous-material-supported CoMo catalysts with different Co/Mo atomic ratios were prepared by coimpregnation of Co(NO3)(2)center dot 6H(2)O and (NH4)(6)Mo(7)O(24)center dot 4H(2)O. The characterization of the catalysts was carried out by X-ray diffraction (XRD), N-2 adsorption/desorption, NH3-temperature-programmed desorption (NH3-TPD), transmission electron microscopy (TEM), CO chemisorption, elemental analysis (EA), and C-13 NMR. MCM-41-supported catalysts showed a small decrease in activity compared to MCM-48-supported catalysts. The optimal Co/Mo atomic ratio for MCM-41- and MCM-48-supported series of catalysts was 3:7. The aluminosilicate-supported CoMo catalysts showed higher activities than their siliceous counterparts. | - |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | Amer Chemical Soc | - |
dc.subject | SILICEOUS MCM-41-SUPPORTED CATALYSTS | - |
dc.subject | MESOPOROUS MOLECULAR-SIEVES | - |
dc.subject | HYDROTHERMAL STABILITY | - |
dc.subject | POTENTIAL APPLICATIONS | - |
dc.subject | MODEL CATALYSTS | - |
dc.subject | MO CATALYSTS | - |
dc.subject | DIBENZOTHIOPHENE | - |
dc.subject | AL-MCM-41 | - |
dc.subject | ACIDITY | - |
dc.subject | NI | - |
dc.title | Characteristics of CoMo catalysts supported on modified MCM-41 and MCM-48 materials for thiophene hydrodesulfurization | - |
dc.type | Article | - |
dc.identifier.wosid | 000234834900009 | - |
dc.identifier.scopusid | 2-s2.0-31544455589 | - |
dc.type.rims | ART | - |
dc.citation.volume | 45 | - |
dc.citation.issue | 2 | - |
dc.citation.beginningpage | 536 | - |
dc.citation.endingpage | 543 | - |
dc.citation.publicationname | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | - |
dc.identifier.doi | 10.1021/ie058064b | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Ihm, Son Ki | - |
dc.contributor.nonIdAuthor | Hussain, M | - |
dc.contributor.nonIdAuthor | Song, SK | - |
dc.contributor.nonIdAuthor | Lee, JH | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | SILICEOUS MCM-41-SUPPORTED CATALYSTS | - |
dc.subject.keywordPlus | MESOPOROUS MOLECULAR-SIEVES | - |
dc.subject.keywordPlus | HYDROTHERMAL STABILITY | - |
dc.subject.keywordPlus | POTENTIAL APPLICATIONS | - |
dc.subject.keywordPlus | MODEL CATALYSTS | - |
dc.subject.keywordPlus | MO CATALYSTS | - |
dc.subject.keywordPlus | DIBENZOTHIOPHENE | - |
dc.subject.keywordPlus | AL-MCM-41 | - |
dc.subject.keywordPlus | ACIDITY | - |
dc.subject.keywordPlus | NI | - |
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