Effects of Ce addition and Pt precursor on the activity of Pt/Al2O3 catalysts for wet oxidation of phenol
The effects of Ce addition on the activity of Pt/Al2O3 catalysts were investigated for the wet oxidation of phenol. Platinum was impregnated on gamma-Al2O3 by using two different precursors: one is anionic (i.e., H2PtCl6) and the other is cationic (i.e., Pt(NH3)(4)Cl-2). The Pt catalysts from the former showed much higher activity than that from the latter, because the former resulted in a better metal dispersion than the latter. Cerium addition lowered the catalytic activity of Pt/Al2O3 catalysts from H2PtCl6, while it improved the activity of Pt/Al2O3 catalysts from Pt(NH3)(4)Cl-2. The effect of Ce addition on the wet oxidation activity of Pt-Ce/Al2O3 could be explained by the differences in Pt dispersion and the Pt-Ce interactions.
- Publisher
- AMER CHEMICAL SOC
- Issue Date
- 2002-04
- Language
- English
- Article Type
- Article
- Keywords
AQUEOUS-SOLUTIONS; CERIUM OXIDE; POLLUTANTS; DECOMPOSITION; PLATINUM; ORGANICS; AMMONIA; OXYGEN; WATER
- Citation
INDUSTRIAL ENGINEERING CHEMISTRY RESEARCH, v.41, no.8, pp.1967 - 1972
- ISSN
- 0888-5885
- Appears in Collection
- CBE-Journal Papers(저널논문)
- Files in This Item
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