DC Field | Value | Language |
---|---|---|
dc.contributor.author | g.myagmarsuren | ko |
dc.contributor.author | ki-soo lee | ko |
dc.contributor.author | o-yong jeong | ko |
dc.contributor.author | Ihm, Son Ki | ko |
dc.date.accessioned | 2008-03-31T06:39:58Z | - |
dc.date.available | 2008-03-31T06:39:58Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2005-03 | - |
dc.identifier.citation | POLYMER, v.46, no.11, pp.3685 - 3692 | - |
dc.identifier.issn | 0032-3861 | - |
dc.identifier.uri | http://hdl.handle.net/10203/3598 | - |
dc.description.abstract | The homopolymerization of 5-alkyl-2-norbornenes and their copolymerization with norbornene have been successfully carried out employing Pd(acac)(2)/PPh3/BF3OEt2 catalyst system. The activity of the catalyst system is comparable to that of most active late-transition metal catalysts described in the literature. The molecular weight distributions of homo- and copolymers indicate a single-site, highly homogeneous character of the active catalyst species. The incorporation of flexible alkyl groups onto the main chain of norbornene as well as copolymerization of 5-alkyl-2-norbornenes with norbornene represent useful methods for lowering the glass transition temperature (T-g), i.e. improving the processability. The simplicity of catalytic system composition might be of industrial importance. © 2005 Elsevier Ltd. All rights reserved. | - |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | Elsevier Sci Ltd | - |
dc.subject | IN-SITU FORMATION | - |
dc.subject | ADDITION POLYMERIZATION | - |
dc.subject | VINYL-POLYMERIZATION | - |
dc.subject | FUNCTIONAL-GROUPS | - |
dc.subject | METAL-CATALYSTS | - |
dc.subject | PRE-CATALYSTS | - |
dc.subject | COMPLEXES | - |
dc.subject | DERIVATIVES | - |
dc.subject | STYRENE | - |
dc.subject | NI | - |
dc.title | Homopolymerization og 5-alkyl-2-norbornene and their copolymerization over novel Pd(acac)2/PPh3/BF3OEt2 catalyst system | - |
dc.type | Article | - |
dc.identifier.wosid | 000229051200016 | - |
dc.identifier.scopusid | 2-s2.0-17544378256 | - |
dc.type.rims | ART | - |
dc.citation.volume | 46 | - |
dc.citation.issue | 11 | - |
dc.citation.beginningpage | 3685 | - |
dc.citation.endingpage | 3692 | - |
dc.citation.publicationname | POLYMER | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Ihm, Son Ki | - |
dc.contributor.nonIdAuthor | g.myagmarsuren | - |
dc.contributor.nonIdAuthor | ki-soo lee | - |
dc.contributor.nonIdAuthor | o-yong jeong | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | alkylnorbornene | - |
dc.subject.keywordAuthor | palladium | - |
dc.subject.keywordAuthor | polymerization | - |
dc.subject.keywordPlus | IN-SITU FORMATION | - |
dc.subject.keywordPlus | ADDITION POLYMERIZATION | - |
dc.subject.keywordPlus | VINYL-POLYMERIZATION | - |
dc.subject.keywordPlus | FUNCTIONAL-GROUPS | - |
dc.subject.keywordPlus | METAL-CATALYSTS | - |
dc.subject.keywordPlus | PRE-CATALYSTS | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | STYRENE | - |
dc.subject.keywordPlus | NI | - |
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