Rechargeable aqueous Zn-ion batteries (AZIBs) are gaining considerable attention as alternatives to Li -ion batteries owing to their excellent safety, high energy density, low cost, and environmental friendliness. However, their Zn anodes suffer from severe dendritic growth, the hydrogen evolution reaction (HER), and corrosion, which limit the commercialization of AZIBs. To address this challenge, we designed a solution involving the development of a high -dielectric hydrophobic BaTiO 3 (BTO) porous scaffold layer that is strategically applied to the Zn surface. This BTO layer effectively impedes the dendritic growth of Zn. The distinct polarizability of the BTO layer actively diminishes the electric -field gradient, thereby minimizing the interaction between the H 2 O molecules and the Zn surface. This phenomenon helps suppress dendritic growth, thus ensuring the uniform deposition of Zn and preventing the HER. The electrochemical performance of a symmetric cell containing the Zn@BTO electrode exhibits low -voltage polarization and stable charge - discharge performance for up to 500 h. In addition, a full -cell AZIB containing a high -capacity alpha-MnO 2 cathode and Zn@BTO anode exhibits good rate capability and a long life of up to 500 cycles. This study demonstrates the development of a cost-effective dendrite -free Zn anode integrated with a highly dielectric hydrophobic BTO porous scaffold layer as a stable Zn - electrolyte interface layer for high-performance AZIBs.