DC Field | Value | Language |
---|---|---|
dc.contributor.author | Yoo, Jaeyoung | ko |
dc.contributor.author | Park, Youngtae | ko |
dc.contributor.author | Choi, Jungwoo | ko |
dc.contributor.author | Roh, Jeonghan | ko |
dc.contributor.author | Shin, Kihyun | ko |
dc.contributor.author | Cho, Hyun-Seok | ko |
dc.contributor.author | Cho, Eunae | ko |
dc.contributor.author | Lee, Changsoo | ko |
dc.contributor.author | Lee, Hyuck Mo | ko |
dc.date.accessioned | 2023-11-14T05:01:36Z | - |
dc.date.available | 2023-11-14T05:01:36Z | - |
dc.date.created | 2023-11-14 | - |
dc.date.created | 2023-11-14 | - |
dc.date.created | 2023-11-14 | - |
dc.date.created | 2023-11-14 | - |
dc.date.issued | 2023-10 | - |
dc.identifier.citation | ACS SUSTAINABLE CHEMISTRY & ENGINEERING, v.11, no.42, pp.15460 - 15469 | - |
dc.identifier.issn | 2168-0485 | - |
dc.identifier.uri | http://hdl.handle.net/10203/314610 | - |
dc.description.abstract | Increasing the electrochemically active surface area (ECSA) and alloying Pt with transition metals (TMs) are well-known strategies for enhancing the oxygen reduction reaction (ORR) catalytic activities. Herein, we introduce a strategy to produce highly active ORR electrocatalysts with a large ECSA using an electrochemical dealloying process involving leaching of Ni from a Ni-rich Pt-Ni nanoparticle network. The dealloying process yielded a dealloyed Pt-Ni nanoparticle network with rugged surfaces from the Ni-rich Pt-Ni nanoparticle network, resulting in a large ECSA. We also increased the mass activity and utilization efficiency of Pt by modulating the interactions between Pt and Ni. The dealloyed nanoparticle network exhibited a high ORR mass activity, six times higher than that of commercial Pt/C. Moreover, the dealloyed Pt-Ni nanoparticle network exhibited better catalytic stability than the Pt/C after 10000 potential cycles, even without carbon support. The reduced binding energy of the O intermediate due to the effects of Ni (ligand and strain effects) enhanced the ORR activity of the dealloyed nanoparticle network, according to the results of a mechanistic study performed using density functional theory. This study opens new avenues for designing TM-alloy catalysts with high ORR activity for various applications. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Electrochemical Dealloying of Ni-Rich Pt-Ni Nanoparticle Network for Robust Oxygen-Reduction Electrocatalysts | - |
dc.type | Article | - |
dc.identifier.wosid | 001090868400001 | - |
dc.identifier.scopusid | 2-s2.0-85177203262 | - |
dc.type.rims | ART | - |
dc.citation.volume | 11 | - |
dc.citation.issue | 42 | - |
dc.citation.beginningpage | 15460 | - |
dc.citation.endingpage | 15469 | - |
dc.citation.publicationname | ACS SUSTAINABLE CHEMISTRY & ENGINEERING | - |
dc.identifier.doi | 10.1021/acssuschemeng.3c04866 | - |
dc.contributor.localauthor | Cho, Eunae | - |
dc.contributor.localauthor | Lee, Hyuck Mo | - |
dc.contributor.nonIdAuthor | Shin, Kihyun | - |
dc.contributor.nonIdAuthor | Cho, Hyun-Seok | - |
dc.contributor.nonIdAuthor | Lee, Changsoo | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | alloy catalyst | - |
dc.subject.keywordAuthor | catalytic stability | - |
dc.subject.keywordAuthor | electrochemicallyactive surface area | - |
dc.subject.keywordAuthor | Ni leaching | - |
dc.subject.keywordAuthor | Pt/transitionmetal alloy | - |
dc.subject.keywordPlus | ALLOY | - |
dc.subject.keywordPlus | SUPPORTLESS | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | NANOWIRES | - |
dc.subject.keywordPlus | NANOTUBES | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | PLATINUM | - |
dc.subject.keywordPlus | SURFACE | - |
dc.subject.keywordPlus | STRAIN | - |
dc.subject.keywordPlus | SKIN | - |
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