DC Field | Value | Language |
---|---|---|
dc.contributor.author | Wang, Lihong | ko |
dc.contributor.author | Sun, Jiaqiong | ko |
dc.contributor.author | Xia, Jiuli | ko |
dc.contributor.author | Li, Mingrui | ko |
dc.contributor.author | Zhang, Lianjin | ko |
dc.contributor.author | Ma, Ruiyang | ko |
dc.contributor.author | Zheng, Guangfan | ko |
dc.contributor.author | Zhang, Qian | ko |
dc.date.accessioned | 2022-10-18T02:00:47Z | - |
dc.date.available | 2022-10-18T02:00:47Z | - |
dc.date.created | 2022-09-19 | - |
dc.date.created | 2022-09-19 | - |
dc.date.issued | 2022-10 | - |
dc.identifier.citation | SCIENCE CHINA-CHEMISTRY, v.65, no.10, pp.1938 - 1944 | - |
dc.identifier.issn | 1674-7291 | - |
dc.identifier.uri | http://hdl.handle.net/10203/299007 | - |
dc.description.abstract | Alkenes are ubiquitous, and the difunctionalization of alkenes represents one of the most practical approaches for the construction of value-added compounds. Dicarbonylation of alkenes provides direct access to value-added 1,4-dicarbonyl compounds. However, selectivity control for unsymmetric 1,2-dicarbonylation is of great challenge. We herein describe NHCs and photocatalysis co-catalyzed three-component radical 1,2-dicarbonylation of alkenes by distinguishing two carbonyl groups, providing structurally diversified 1,4-diketones. Distinct properties of acyl radical and NHCs-stabilized ketyl radical contributed to selectivity control. Acyl radicals are rapidly added to alkenes delivering alkyl radicals, which undergo subsequent radical-radical cross-coupling with NHCs-stabilized ketyl-type radicals, affording 1,2-dicarbonylation products. This transformation features mild reaction conditions, broad substrate scope, and excellent selectivity, providing a general and practical approach for the dicarbonylation of olefins. | - |
dc.language | English | - |
dc.publisher | SCIENCE PRESS | - |
dc.title | Visible light-mediated NHCs and photoredox co-catalyzed radical 1,2-dicarbonylation of alkenes for 1,4-diketones | - |
dc.type | Article | - |
dc.identifier.wosid | 000850759500001 | - |
dc.identifier.scopusid | 2-s2.0-85137471664 | - |
dc.type.rims | ART | - |
dc.citation.volume | 65 | - |
dc.citation.issue | 10 | - |
dc.citation.beginningpage | 1938 | - |
dc.citation.endingpage | 1944 | - |
dc.citation.publicationname | SCIENCE CHINA-CHEMISTRY | - |
dc.identifier.doi | 10.1007/s11426-022-1328-5 | - |
dc.contributor.nonIdAuthor | Wang, Lihong | - |
dc.contributor.nonIdAuthor | Sun, Jiaqiong | - |
dc.contributor.nonIdAuthor | Xia, Jiuli | - |
dc.contributor.nonIdAuthor | Li, Mingrui | - |
dc.contributor.nonIdAuthor | Ma, Ruiyang | - |
dc.contributor.nonIdAuthor | Zheng, Guangfan | - |
dc.contributor.nonIdAuthor | Zhang, Qian | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | NHCs | - |
dc.subject.keywordAuthor | photocatalysis | - |
dc.subject.keywordAuthor | radical 1 | - |
dc.subject.keywordAuthor | 2-dicarbonylation | - |
dc.subject.keywordAuthor | alkenes | - |
dc.subject.keywordAuthor | 1 | - |
dc.subject.keywordAuthor | 4-diketones | - |
dc.subject.keywordPlus | ACYLATION | - |
dc.subject.keywordPlus | METAL | - |
dc.subject.keywordPlus | DIACYLATION | - |
dc.subject.keywordPlus | STYRENES | - |
dc.subject.keywordPlus | ENONES | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.