The effect of ethylene carbonate on the cycling performance of a Si electrode

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dc.contributor.authorProfatilova, I. A.ko
dc.contributor.authorChoi, Nam-Soonko
dc.contributor.authorYew, Kyoung Hanko
dc.contributor.authorChoi, Wan-Ukko
dc.date.accessioned2021-08-20T06:31:22Z-
dc.date.available2021-08-20T06:31:22Z-
dc.date.created2021-08-20-
dc.date.created2021-08-20-
dc.date.created2021-08-20-
dc.date.issued2008-12-
dc.identifier.citationSOLID STATE IONICS, v.179, no.40, pp.2399 - 2405-
dc.identifier.issn0167-2738-
dc.identifier.urihttp://hdl.handle.net/10203/287286-
dc.description.abstractThe electrochemical cycling properties of a Si electrode were drastically improved by the introduction of an ethylene carbonate (EC)-rich electrolyte solution. Cross-sectional morphologies of fully charged Si electrodes were observed with scanning electron microscopy (SEM). The increment of EC in the electrolyte solution showed a tendency to prohibit the deterioration of the Si electrode during Li+ ion insertion. We analyzed the surface films formed on a Si electrode through Fourier transform infrared (FT-IR) spectroscopy. The solvation shell structures of Li+ ions in electrolyte solutions were studied with FT-IR spectroscopy, and the apparent solvation numbers for Li+ ions by EC molecules were calculated. (C) 2008 Elsevier B.V. All rights reserved.-
dc.languageEnglish-
dc.publisherELSEVIER SCIENCE BV-
dc.titleThe effect of ethylene carbonate on the cycling performance of a Si electrode-
dc.typeArticle-
dc.identifier.wosid000262895600013-
dc.identifier.scopusid2-s2.0-57849148895-
dc.type.rimsART-
dc.citation.volume179-
dc.citation.issue40-
dc.citation.beginningpage2399-
dc.citation.endingpage2405-
dc.citation.publicationnameSOLID STATE IONICS-
dc.identifier.doi10.1016/j.ssi.2008.10.004-
dc.contributor.localauthorChoi, Nam-Soon-
dc.contributor.nonIdAuthorProfatilova, I. A.-
dc.contributor.nonIdAuthorYew, Kyoung Han-
dc.contributor.nonIdAuthorChoi, Wan-Uk-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorSilicon electrode-
dc.subject.keywordAuthorCarbonate-based electrolyte-
dc.subject.keywordAuthorElectrode morphology-
dc.subject.keywordAuthorCracking phenomena-
dc.subject.keywordAuthorFT-IR spectroscopy-
dc.subject.keywordAuthorLi+ ions salvation shell-
dc.subject.keywordPlusLITHIUM-ION BATTERIES-
dc.subject.keywordPlusTHIN-FILM ELECTRODE-
dc.subject.keywordPlusPROPYLENE CARBONATE-
dc.subject.keywordPlusLI-ION-
dc.subject.keywordPlusLIQUID ELECTROLYTES-
dc.subject.keywordPlusAMORPHOUS-SILICON-
dc.subject.keywordPlusSOLVENT SYSTEMS-
dc.subject.keywordPlusNANO-SILICON-
dc.subject.keywordPlusANODES-
dc.subject.keywordPlusPERCHLORATE-
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