Pd3Pb Nanosponges for Selective Conversion of Furfural to Furfuryl Alcohol under Mild Condition

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Alloy structures with high catalytic surface areas and tunable surface energies can lead to high catalytic selectivity and activities. Herein, the synthesis of sponge-like Pd3Pb multiframes (Pd3Pb MFs) is reported by using the thermodynamically driven phase segregation, which exhibit high selectivity (93%) for the conversion of furfural to furfuryl alcohol (FOL) under mild conditions. The excellent catalytic performance of the Pd3Pb MF catalysts is attributed to the high surface area and optimized surface energy of the catalyst, which is associated with the introduction of Pb to Pd. Density functional theory calculations show that the binding energy of FOL to the surface energy-tuned Pd3Pb MF is sufficiently lowered to prevent side reactions such as over-hydrogenation of FOL.
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2021-07
Language
English
Article Type
Article
Citation

SMALL METHODS, v.5, no.7, pp.2100400

ISSN
2366-9608
DOI
10.1002/smtd.202100400
URI
http://hdl.handle.net/10203/286930
Appears in Collection
CBE-Journal Papers(저널논문)
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