DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kholodkov, Dmitry N. | ko |
dc.contributor.author | Eremchuk, Kseniia I. | ko |
dc.contributor.author | Soldatkin, Yuri V. | ko |
dc.contributor.author | Volodin, Alexander D. | ko |
dc.contributor.author | Korlyukov, Alexander A. | ko |
dc.contributor.author | Anisimov, Anton A. | ko |
dc.contributor.author | Novikov, Roman A. | ko |
dc.contributor.author | Arzumanyan, Ashot V. | ko |
dc.date.accessioned | 2021-06-21T06:10:10Z | - |
dc.date.available | 2021-06-21T06:10:10Z | - |
dc.date.created | 2021-06-21 | - |
dc.date.created | 2021-06-21 | - |
dc.date.issued | 2021-06 | - |
dc.identifier.citation | NEW JOURNAL OF CHEMISTRY, v.45, no.22, pp.9805 - 9810 | - |
dc.identifier.issn | 1144-0546 | - |
dc.identifier.uri | http://hdl.handle.net/10203/286009 | - |
dc.description.abstract | A series of hydrophobic/hydrophilic well-defined stereoregular cyclic structures-p-tolyl-siloxanes with alkyl, O- and N-containing groups-were obtained as promising reagents for the synthesis of functionalized derivatives. This approach is based on the preparation of a stereoregular cyclic p-tolyl-siloxane with a Si-H group (1) followed by hydrosilylation of 1-octene, allyl glycol ethers and alcohol or allylamine derivatives (2a-g). The method is well scalable and allows the target products (3a-g) to be obtained on a gram scale (similar to 10 g) in 60-95% yields. The structure of the compounds was confirmed by a set of physicochemical methods of analysis, namely IR, ESI-HRMS, GPC, 1D and 2D H-1, C-13, and Si-29 NMR experiments, and X-Ray diffraction for cyclic p-tolyl- and hydride-containing siloxane (1). | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Stereoregular cyclic p-tolyl-siloxanes with alkyl, O- and N-containing groups as promising reagents for the synthesis of functionalized organosiloxanes | - |
dc.type | Article | - |
dc.identifier.wosid | 000658494300009 | - |
dc.identifier.scopusid | 2-s2.0-85107624183 | - |
dc.type.rims | ART | - |
dc.citation.volume | 45 | - |
dc.citation.issue | 22 | - |
dc.citation.beginningpage | 9805 | - |
dc.citation.endingpage | 9810 | - |
dc.citation.publicationname | NEW JOURNAL OF CHEMISTRY | - |
dc.identifier.doi | 10.1039/d1nj01222c | - |
dc.contributor.localauthor | Eremchuk, Kseniia I. | - |
dc.contributor.nonIdAuthor | Kholodkov, Dmitry N. | - |
dc.contributor.nonIdAuthor | Soldatkin, Yuri V. | - |
dc.contributor.nonIdAuthor | Volodin, Alexander D. | - |
dc.contributor.nonIdAuthor | Korlyukov, Alexander A. | - |
dc.contributor.nonIdAuthor | Anisimov, Anton A. | - |
dc.contributor.nonIdAuthor | Novikov, Roman A. | - |
dc.contributor.nonIdAuthor | Arzumanyan, Ashot V. | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | POLY(ETHYLENE GLYCOL) | - |
dc.subject.keywordPlus | POLYETHYLENE | - |
dc.subject.keywordPlus | STRATEGIES | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | WELL | - |
dc.subject.keywordPlus | PDMS | - |
dc.subject.keywordPlus | PEG | - |
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