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Iridium-Catalyzed Cyclative Indenylation and Dienylation through Sequential B(4)-C Bond Formation, Cyclization, and Elimination from o-Carboranes and Propargyl Alcohols

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dc.contributor.authorBaek, Yonghyeonko
dc.contributor.authorCheong, Kiunko
dc.contributor.authorKo, Gi Hoonko
dc.contributor.authorHan, Gi Ukko
dc.contributor.authorHan, Sang Hoonko
dc.contributor.authorKim, Dongwookko
dc.contributor.authorLee, Kooyeonko
dc.contributor.authorLee, Phil Hoko
dc.date.accessioned2021-03-26T03:13:13Z-
dc.date.available2021-03-26T03:13:13Z-
dc.date.created2020-06-29-
dc.date.issued2020-06-
dc.identifier.citationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.142, no.22, pp.9890 - 9895-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10203/282024-
dc.description.abstractDescribed herein is the first iridium-catalyzed cyclative indenylation through sequential B(4)-C and intramolecular C-C bond formation from o-carboranes and propargyl alcohols, leading to the formation of B(4)-indenylated o-carboranes with excellent regioselectivity via direct B-H activation. Moreover, the iridium-catalyzed regioselective 1,3-dienylation has been accessed through sequential B-H activation, dehydration, and decarboxylation, producing B(4)-dienylated o-carboranes.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.titleIridium-Catalyzed Cyclative Indenylation and Dienylation through Sequential B(4)-C Bond Formation, Cyclization, and Elimination from o-Carboranes and Propargyl Alcohols-
dc.typeArticle-
dc.identifier.wosid000538526500003-
dc.identifier.scopusid2-s2.0-85085908627-
dc.type.rimsART-
dc.citation.volume142-
dc.citation.issue22-
dc.citation.beginningpage9890-
dc.citation.endingpage9895-
dc.citation.publicationnameJOURNAL OF THE AMERICAN CHEMICAL SOCIETY-
dc.identifier.doi10.1021/jacs.0c02121-
dc.contributor.nonIdAuthorBaek, Yonghyeon-
dc.contributor.nonIdAuthorCheong, Kiun-
dc.contributor.nonIdAuthorKo, Gi Hoon-
dc.contributor.nonIdAuthorHan, Gi Uk-
dc.contributor.nonIdAuthorHan, Sang Hoon-
dc.contributor.nonIdAuthorLee, Kooyeon-
dc.contributor.nonIdAuthorLee, Phil Ho-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordPlusCAGE B-H-
dc.subject.keywordPlusBORON CLUSTERS-
dc.subject.keywordPlusDRUG DISCOVERY-
dc.subject.keywordPlusACTIVATION-
dc.subject.keywordPlusCHEMISTRY-
dc.subject.keywordPlusFUNCTIONALIZATION-
dc.subject.keywordPlusALLENYLATION-
dc.subject.keywordPlusAROMATICITY-
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