DC Field | Value | Language |
---|---|---|
dc.contributor.author | Park, Jae Hyun | ko |
dc.contributor.author | Choi, Wonyeong | ko |
dc.contributor.author | Yang, Jeongwoo | ko |
dc.contributor.author | Kim, Do Hyeun | ko |
dc.contributor.author | Gim, Hyeonseo | ko |
dc.contributor.author | Lee, Jae Woo | ko |
dc.date.accessioned | 2021-01-14T02:10:07Z | - |
dc.date.available | 2021-01-14T02:10:07Z | - |
dc.date.created | 2020-10-29 | - |
dc.date.issued | 2021-02 | - |
dc.identifier.citation | CARBON, v.172, pp.624 - 636 | - |
dc.identifier.issn | 0008-6223 | - |
dc.identifier.uri | http://hdl.handle.net/10203/279908 | - |
dc.description.abstract | A free-standing cathode without any binder, conductor, and current collector is attractive due to its reduced weight and cost. This study introduces nitrogen-rich and hierarchical porous carbon fibers in the form of a free-standing carbon paper synthesized by NaBH4-aided electrospinning and subsequent CO2 annealing. This modified process leads to a large mesopore volume of 1.007 cm(3) g(-1) and exposes the nitrogen inside the polymer to the surface of the fiber, resulting in the outstanding surface nitrogen content of 19.38 wt% with abundant pyridinic-N and pyrrolic-N of 16.24 wt% in total surface atoms, while eliminating any further treatment for increasing porosity or coating the polar active sites. The resultant material impregnated by sulfur and filtered by a graphene solution is directly employed as a cathode without any additives. As a result, the capacity is maintained at 696 mAh g(-1) up to the 500th cycle at 0.2 C, and 645 mAh g(-1) at a high current density of 5.0 C. Even with a high sulfur loading of 6.11 mg cm(-2), a remarkable areal capacity of 3.09 mAh cm(-2) is recorded after 500 cycles at 0.2 C with the free-standing form preserved. | - |
dc.language | English | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.title | Nitrogen-rich hierarchical porous carbon paper for a free-standing cathode of lithium sulfur battery | - |
dc.type | Article | - |
dc.identifier.wosid | 000600356800009 | - |
dc.identifier.scopusid | 2-s2.0-85094324159 | - |
dc.type.rims | ART | - |
dc.citation.volume | 172 | - |
dc.citation.beginningpage | 624 | - |
dc.citation.endingpage | 636 | - |
dc.citation.publicationname | CARBON | - |
dc.identifier.doi | 10.1016/j.carbon.2020.10.078 | - |
dc.contributor.localauthor | Lee, Jae Woo | - |
dc.contributor.nonIdAuthor | Kim, Do Hyeun | - |
dc.contributor.nonIdAuthor | Gim, Hyeonseo | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Electrospinning | - |
dc.subject.keywordAuthor | Free-standing | - |
dc.subject.keywordAuthor | N-rich carbon | - |
dc.subject.keywordAuthor | Hierarchical structure | - |
dc.subject.keywordAuthor | Li-S battery Cathode | - |
dc.subject.keywordPlus | LI-S BATTERIES | - |
dc.subject.keywordPlus | COMPOSITE FILM | - |
dc.subject.keywordPlus | LONG-LIFE | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | POLYSULFIDE | - |
dc.subject.keywordPlus | OXIDE | - |
dc.subject.keywordPlus | DIOXIDE | - |
dc.subject.keywordPlus | CO2 | - |
dc.subject.keywordPlus | CHEMISORPTION | - |
dc.subject.keywordPlus | NANOFIBERS | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.