DC Field | Value | Language |
---|---|---|
dc.contributor.author | KIM, JS | ko |
dc.contributor.author | Woo, Seong-Ihl | ko |
dc.date.accessioned | 2019-03-06T19:39:28Z | - |
dc.date.available | 2019-03-06T19:39:28Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 1994-03 | - |
dc.identifier.citation | APPLIED CATALYSIS A-GENERAL, v.110, no.2, pp.173 - 184 | - |
dc.identifier.issn | 0926-860X | - |
dc.identifier.uri | http://hdl.handle.net/10203/250739 | - |
dc.description.abstract | The ammoxidation of propane to acrylonitrile was investigated over Ca-Bi molybdate oxide catalysts (CaxBi12-xMo12 oxide). The performance of the catalysts changed as a function of the oxide composition. The highest performance for the ammoxidation reaction was obtained around x = 6 in CaxBi12-xMo12 oxide catalyst. The maximum selectivity of acrylonitrile and conversion of propane were 63% and 15%, respectively. The maximum selectivity of acrylonitrile was obtained at a propane concentration of 50-70% and a O2/NH3 mole ratio of about 1.5 in the feed. It was found that the initial step of propane ammoxidation was the formation of a gas-phase propyl radical which would be subsequently converted to propene and acrylonitrile by a catalytic surface reaction. | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.subject | HETEROGENEOUS STEPS | - |
dc.subject | BISMUTH MOLYBDATES | - |
dc.subject | OXIDATION | - |
dc.subject | PHASE | - |
dc.subject | COOPERATION | - |
dc.title | SELECTIVE AMMOXIDATION OF PROPANE OVER CA-BI-MO OXIDE CATALYST | - |
dc.type | Article | - |
dc.identifier.wosid | A1994NE70300003 | - |
dc.identifier.scopusid | 2-s2.0-0028401328 | - |
dc.type.rims | ART | - |
dc.citation.volume | 110 | - |
dc.citation.issue | 2 | - |
dc.citation.beginningpage | 173 | - |
dc.citation.endingpage | 184 | - |
dc.citation.publicationname | APPLIED CATALYSIS A-GENERAL | - |
dc.contributor.localauthor | Woo, Seong-Ihl | - |
dc.contributor.nonIdAuthor | KIM, JS | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | ACRYLONITRILE | - |
dc.subject.keywordAuthor | AMMOXIDATION | - |
dc.subject.keywordAuthor | CA-BI-MO OXIDE | - |
dc.subject.keywordAuthor | PROPANE | - |
dc.subject.keywordPlus | HETEROGENEOUS STEPS | - |
dc.subject.keywordPlus | BISMUTH MOLYBDATES | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | PHASE | - |
dc.subject.keywordPlus | COOPERATION | - |
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