Bismuth sulfonate immobilized on silica gel for allylation of aldehydes and synthesis of homoallylic amines

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Catalytic allylation of aldehydes and the synthesis of homoallylic amines using bismuth sulfonate immobilized on silica gel in presence of allyltributylstannane are reported for the first time. The reaction proceeds smoothly with the aid of benzoic acid as an additive and provides corresponding homoallylic alcohols and homoallylic amines in good yields. The catalyst can be reused five times without significant loss of the catalytic activity. Bismuth Sulfonate Immobilized on Silica gel for Allylation of Aldehydes and Synthesis of Homoallylic Amines. [GRAPHICS]
Publisher
KLUWER ACADEMIC/PLENUM PUBL
Issue Date
2004-07
Language
English
Article Type
Article
Citation

CATALYSIS LETTERS, v.96, no.3-4, pp.201 - 204

ISSN
1011-372X
DOI
10.1023/B:CATL.0000030121.59482.6d
URI
http://hdl.handle.net/10203/247691
Appears in Collection
CBE-Journal Papers(저널논문)
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