DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Yun Hyeok | ko |
dc.contributor.author | Choi, Gwang Mun | ko |
dc.contributor.author | Bae, Jin Gyu | ko |
dc.contributor.author | Kim, Yongho | ko |
dc.contributor.author | Bae, Byeong-Soo | ko |
dc.date.accessioned | 2018-07-24T03:00:25Z | - |
dc.date.available | 2018-07-24T03:00:25Z | - |
dc.date.created | 2018-06-15 | - |
dc.date.created | 2018-06-15 | - |
dc.date.issued | 2018-04 | - |
dc.identifier.citation | POLYMER, v.10, no.4 | - |
dc.identifier.issn | 2073-4360 | - |
dc.identifier.uri | http://hdl.handle.net/10203/244587 | - |
dc.description.abstract | A high performance ladder-like structured methacrylate siloxane hybrid material (LMSH) was fabricated via simple hydrolytic sol-gel reaction, followed by free-radical polymerization. A structurally ordered siloxane backbone, the ladder-like structure, which is an essential factor for high performance, could be achieved by a short period of sol-gel reaction in only 4 h. This results in superior optical (Transmittance > 90% at 550 nm), thermal (T-5 wt % decomposition > 400), mechanical properties(elastic recovery = 0.86, hardness = 0.6 GPa) compared to the random- and even commercialized cage-structured silsesquioxane, which also has ordered structure. It was investigated that the fabricated ladder-like structured MSH showed the highest overall density of organic/inorganic co-networks that are originated from highly ordered siloxane network, along with high conversion rate of polymerizable methacrylate groups. Our findings suggest a potential of the ladder-like structured MSH as a powerful alternative for the methacrylate polysilsesquioxane, which can be applied to thermally stable and flexible optical coatings, even with an easier and simpler preparation process. | - |
dc.language | English | - |
dc.publisher | MDPI | - |
dc.title | High-Performance and Simply-Synthesized Ladder-Like Structured Methacrylate Siloxane Hybrid Material for Flexible Hard Coating | - |
dc.type | Article | - |
dc.identifier.wosid | 000435087400107 | - |
dc.identifier.scopusid | 2-s2.0-85045729437 | - |
dc.type.rims | ART | - |
dc.citation.volume | 10 | - |
dc.citation.issue | 4 | - |
dc.citation.publicationname | POLYMER | - |
dc.identifier.doi | 10.3390/polym10040449 | - |
dc.contributor.localauthor | Bae, Byeong-Soo | - |
dc.contributor.nonIdAuthor | Bae, Jin Gyu | - |
dc.description.isOpenAccess | Y | - |
dc.type.journalArticle | Article | - |
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