Epoxidation of olefins over thermally stable polyimide-supported Mo(VI) complexes
Polyimide particulates carrying a functional group have been prepared by non-aqueous suspension polycondensation. Molybdenum(VI) complex has been supported on a functional polyimide bead and used as a catalyst in the liquid-phase epoxidation of cyclohexene with tert-butylhydroperoxide (TBHP), as oxygen source. The polyimide-supported Mo catalyst was highly active and selective, and has been recycled 10 times with no detectable loss of Mo from the support.
- Publisher
- ELSEVIER SCIENCE PUBL B V
- Issue Date
- 1997
- Language
- English
- Article Type
- Article; Proceedings Paper
- Keywords
IMIDAZOLE-CONTAINING POLYMERS; CYCLOHEXENE; CATALYSTS
- Citation
3RD WORLD CONGRESS ON OXIDATION CATALYSIS Book Series: STUDIES IN SURFACE SCIENCE AND CATALYSIS, v.110, pp.957 - 964
- ISSN
- 0167-2991
- Appears in Collection
- CBE-Journal Papers(저널논문)
- Files in This Item
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