DC Field | Value | Language |
---|---|---|
dc.contributor.author | Nam, W | ko |
dc.contributor.author | Goh, YM | ko |
dc.contributor.author | Lee, YJ | ko |
dc.contributor.author | Lim, Mi Hee | ko |
dc.contributor.author | Kim, C | ko |
dc.date.accessioned | 2018-02-21T06:26:00Z | - |
dc.date.available | 2018-02-21T06:26:00Z | - |
dc.date.created | 2018-02-08 | - |
dc.date.created | 2018-02-08 | - |
dc.date.created | 2018-02-08 | - |
dc.date.issued | 1999-06 | - |
dc.identifier.citation | INORGANIC CHEMISTRY, v.38, no.13, pp.3238 - + | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | http://hdl.handle.net/10203/240353 | - |
dc.description.abstract | An iron(III) porphyrin complex with highly electron-withdrawing substituents on the porphyrin ligand efficiently catalyzes the hydroxylation of alkanes by H2O2 via enzyme mimetic oxidation reactions in aprotic solvent. An "isolated" high-valent iron(IV) oxo porphyrin cation radical intermediate, prepared in situ by reaction of the iron porphyrin complex with m-CPBA at -40 degrees C, is capable of activating C-H bonds of alkanes to give oxygenated products efficiently. The hydroxylating intermediate generated in the catalytic H2O2 reaction is evidenced to be the high-valent iron(IV) oxo porphyrin cation radical species. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Biomimetic alkane hydroxylations by an iron(III) porphyrin complex with H2O2 and by a high-valent iron(IV) oxo porphyrin cation radical complex | - |
dc.type | Article | - |
dc.identifier.wosid | 000081189300033 | - |
dc.type.rims | ART | - |
dc.citation.volume | 38 | - |
dc.citation.issue | 13 | - |
dc.citation.beginningpage | 3238 | - |
dc.citation.endingpage | + | - |
dc.citation.publicationname | INORGANIC CHEMISTRY | - |
dc.identifier.doi | 10.1021/ic980670u | - |
dc.contributor.localauthor | Lim, Mi Hee | - |
dc.contributor.nonIdAuthor | Nam, W | - |
dc.contributor.nonIdAuthor | Goh, YM | - |
dc.contributor.nonIdAuthor | Lee, YJ | - |
dc.contributor.nonIdAuthor | Kim, C | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | WATER-SOLUBLE METALLOPORPHYRINS | - |
dc.subject.keywordPlus | AQUEOUS-SOLUTION | - |
dc.subject.keywordPlus | CATALYZED HYDROXYLATION | - |
dc.subject.keywordPlus | HYDROGEN-PEROXIDE | - |
dc.subject.keywordPlus | OXYGEN-ATOM | - |
dc.subject.keywordPlus | CYTOCHROME-P-450 | - |
dc.subject.keywordPlus | HYDROCARBONS | - |
dc.subject.keywordPlus | EPOXIDATION | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | OLEFINS | - |
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