Characterization of pyridinylimine and pyridinylmethylamine derivatives and their corresponding metal complexese

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dc.contributor.authorBraymer, Joseph J.ko
dc.contributor.authorMerrill, Nathan M.ko
dc.contributor.authorLim, Mi Heeko
dc.date.accessioned2018-02-21T06:24:57Z-
dc.date.available2018-02-21T06:24:57Z-
dc.date.created2018-02-08-
dc.date.created2018-02-08-
dc.date.created2018-02-08-
dc.date.issued2012-01-
dc.identifier.citationINORGANICA CHIMICA ACTA, v.380, pp.261 - 268-
dc.identifier.issn0020-1693-
dc.identifier.urihttp://hdl.handle.net/10203/240311-
dc.description.abstractBidentate pyridinylimine (L1-a and L1-b) and pyridinylmethylamine (L2-a and L2-b) derivatives have recently received attention due to their potential use as chemical reagants that can target metal-associated amyloid-beta (A beta) species and modulate metal-induced A beta aggregation and neurotoxicity in vitro and in living cells. Herein, we report the characterization of these bidentate ligands and their corresponding metal complexes by X-ray crystallography and spectroscopic methods, including UV-Vis spectroscopy (UV-Vis), nuclear magnetic resonance spectroscopy (NMR), and Fourier transform infrared spectroscopy (FT-IR). Our studies presented how the different structural moieties of ligand frameworks (L1-a, L1-b, L2-a, and L2-b), in addition to effects of metal binding, contribute to variations in structure and chemical environments of the ligands and their corresponding metal complexes. (C) 2011 Elsevier B.V. All rights reserved.-
dc.languageEnglish-
dc.publisherELSEVIER SCIENCE SA-
dc.titleCharacterization of pyridinylimine and pyridinylmethylamine derivatives and their corresponding metal complexese-
dc.typeArticle-
dc.identifier.wosid000300180100035-
dc.identifier.scopusid2-s2.0-84856232089-
dc.type.rimsART-
dc.citation.volume380-
dc.citation.beginningpage261-
dc.citation.endingpage268-
dc.citation.publicationnameINORGANICA CHIMICA ACTA-
dc.identifier.doi10.1016/j.ica.2011.08.056-
dc.contributor.localauthorLim, Mi Hee-
dc.contributor.nonIdAuthorBraymer, Joseph J.-
dc.contributor.nonIdAuthorMerrill, Nathan M.-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorBioinorganic chemistry-
dc.subject.keywordAuthorMetal complexes of pyridinylimine and pyridinylmethylamine derivatives-
dc.subject.keywordAuthorSpectroscopic studies-
dc.subject.keywordAuthorX-ray crystal structure determination-
dc.subject.keywordPlusBETA-AMYLOID PLAQUES-
dc.subject.keywordPlusALZHEIMERS-DISEASE-
dc.subject.keywordPlusTRANSGENIC MICE-
dc.subject.keywordPlusA-BETA-
dc.subject.keywordPlusBINDING-
dc.subject.keywordPlusDESIGN-
dc.subject.keywordPlusLIGAND-
dc.subject.keywordPlusACCUMULATION-
dc.subject.keywordPlusSTABILITY-
dc.subject.keywordPlusQUINOLINE-
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