Synthesis of Tetrahexahedral Gold Nanocrystals with High-Index Facets

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Tetrahexahedral (THH) gold nanocrystals bound to 24 high-index facets were synthesized through a facile colloidal chemistry by reducing HAuCl(4) in the mixture solution of N,N-dimethylformamide and poly(vinylpyrrolidone) at 80 degrees C. As-synthesized THH gold nanocrystals with O(h) symmetry were single-crystals, mainly bound to 24 high-index (210) facets. The controlled slow reaction condition made the rhombic dodecahedral gold nanocrystals transform to THH gold nanocrystals with high-index facets.
Publisher
AMER CHEMICAL SOC
Issue Date
2010-08
Language
English
Article Type
Article
Keywords

SURFACES; CATALYSIS; NANOPARTICLES; CHEMISTRY; SHAPES

Citation

CRYSTAL GROWTH DESIGN, v.10, no.8, pp.3321 - 3323

ISSN
1528-7483
DOI
10.1021/cg100639s
URI
http://hdl.handle.net/10203/23822
Appears in Collection
CBE-Journal Papers(저널논문)
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