DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kuk, Su Keun | ko |
dc.contributor.author | Singh, Raushan K. | ko |
dc.contributor.author | Nam, Dong-Heon | ko |
dc.contributor.author | Singh, Ranjitha | ko |
dc.contributor.author | Lee, Jung-Kul | ko |
dc.contributor.author | Park, Chan Beum | ko |
dc.date.accessioned | 2017-04-17T07:27:23Z | - |
dc.date.available | 2017-04-17T07:27:23Z | - |
dc.date.created | 2017-04-10 | - |
dc.date.created | 2017-04-10 | - |
dc.date.issued | 2017-03 | - |
dc.identifier.citation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.56, no.14, pp.3827 - 3832 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10203/223247 | - |
dc.description.abstract | Natural photosynthesis is an effective route for the clean and sustainable conversion of CO2 into high-energy chemicals. Inspired by the natural process, a tandem photo-electrochemical (PEC) cell with an integrated enzyme-cascade (TPIEC) system was designed, which transfers photogenerated electrons to a multienzyme cascade for the biocatalyzed reduction of CO2 to methanol. A hematite photoanode and a bismuth ferrite photocathode were applied to fabricate the iron oxide based tandem PEC cell for visible-light-assisted regeneration of the nicotinamide cofactor (NADH). The cell utilized water as an electron donor and spontaneously regenerated NADH. To complete the TPIEC system, a superior three-dehydrogenase cascade system was employed in the cathodic part of the PEC cell. Under applied bias, the TPIEC system achieved a high methanol conversion output of 220 mu mh(-1), 1280 mu molg(-1)h(-1) using readily available solar energy and water. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | VISIBLE-LIGHT IRRADIATION | - |
dc.subject | CO2 REDUCTION | - |
dc.subject | ARTIFICIAL PHOTOSYNTHESIS | - |
dc.subject | ELECTROCHEMICAL REDUCTION | - |
dc.subject | PHOTOCATALYTIC REDUCTION | - |
dc.subject | PHOTOCHEMICAL REDUCTION | - |
dc.subject | REDOX BIOCATALYSIS | - |
dc.subject | CONVERTING CO2 | - |
dc.subject | ENERGY | - |
dc.subject | CELLS | - |
dc.title | Photoelectrochemical Reduction of Carbon Dioxide to Methanol through a Highly Efficient Enzyme Cascade | - |
dc.type | Article | - |
dc.identifier.wosid | 000397346200006 | - |
dc.identifier.scopusid | 2-s2.0-85015927504 | - |
dc.type.rims | ART | - |
dc.citation.volume | 56 | - |
dc.citation.issue | 14 | - |
dc.citation.beginningpage | 3827 | - |
dc.citation.endingpage | 3832 | - |
dc.citation.publicationname | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.identifier.doi | 10.1002/anie.201611379 | - |
dc.contributor.localauthor | Park, Chan Beum | - |
dc.contributor.nonIdAuthor | Singh, Raushan K. | - |
dc.contributor.nonIdAuthor | Singh, Ranjitha | - |
dc.contributor.nonIdAuthor | Lee, Jung-Kul | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | biocatalysis | - |
dc.subject.keywordAuthor | CO2 reduction | - |
dc.subject.keywordAuthor | enzymes | - |
dc.subject.keywordAuthor | methanol production | - |
dc.subject.keywordAuthor | photosynthesis | - |
dc.subject.keywordPlus | VISIBLE-LIGHT IRRADIATION | - |
dc.subject.keywordPlus | CO2 REDUCTION | - |
dc.subject.keywordPlus | ARTIFICIAL PHOTOSYNTHESIS | - |
dc.subject.keywordPlus | ELECTROCHEMICAL REDUCTION | - |
dc.subject.keywordPlus | PHOTOCATALYTIC REDUCTION | - |
dc.subject.keywordPlus | PHOTOCHEMICAL REDUCTION | - |
dc.subject.keywordPlus | REDOX BIOCATALYSIS | - |
dc.subject.keywordPlus | CONVERTING CO2 | - |
dc.subject.keywordPlus | ENERGY | - |
dc.subject.keywordPlus | CELLS | - |
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