Enzymatic regioselective synthesis of sucrose acrylate esters

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dc.contributor.authorPark, Hyun Gyuko
dc.contributor.authorChang, Ho Namko
dc.date.accessioned2010-12-14T02:33:02Z-
dc.date.available2010-12-14T02:33:02Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2000-01-
dc.identifier.citationBIOTECHNOLOGY LETTERS, v.22, no.1, pp.39 - 42-
dc.identifier.issn0141-5492-
dc.identifier.urihttp://hdl.handle.net/10203/21004-
dc.description.abstractUsing a protease (at 100 g l(-1)) from Bacillus licheniformis, enzymatic acryloylation of sucrose (1 M) with vinyl acrylate (4 M) was carried out in anhydrous pyridine and yielded sucrose acrylate esters with more than 90% of sucrose converted in 24 h. After 5 days of reaction, the ester products consisted of 70% sucrose monoacrylate and 30% sucrose diacrylate. The monoester product was a sucrose 1'-acrylate and the diester products consisted of sucrose 6,1'-diacrylate and sucrose 6',1'-diacrylate in the ratio of 3:2.-
dc.description.sponsorshipThe authors are grateful to the Korea Science and Engineering Foundation for financial support.en
dc.languageEnglish-
dc.language.isoen_USen
dc.publisherKLUWER ACADEMIC PUBL-
dc.subjectORGANIC-SOLVENTS-
dc.subjectCHEMOENZYMATIC SYNTHESIS-
dc.subject2&apos-
dc.subject-DEOXYCOFORMYCIN-
dc.subjectBIOSYNTHESIS-
dc.titleEnzymatic regioselective synthesis of sucrose acrylate esters-
dc.typeArticle-
dc.identifier.wosid000084642100008-
dc.identifier.scopusid2-s2.0-0001780228-
dc.type.rimsART-
dc.citation.volume22-
dc.citation.issue1-
dc.citation.beginningpage39-
dc.citation.endingpage42-
dc.citation.publicationnameBIOTECHNOLOGY LETTERS-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorPark, Hyun Gyu-
dc.contributor.localauthorChang, Ho Nam-
dc.type.journalArticleArticle-
dc.subject.keywordAuthoracrylate-
dc.subject.keywordAuthorenzymatic synthesis-
dc.subject.keywordAuthorprotease-
dc.subject.keywordAuthorsucrose-
dc.subject.keywordPlusORGANIC-SOLVENTS-
dc.subject.keywordPlusCHEMOENZYMATIC SYNTHESIS-
dc.subject.keywordPlus2&apos-
dc.subject.keywordPlus-DEOXYCOFORMYCIN-
dc.subject.keywordPlusBIOSYNTHESIS-
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