DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jo, Seung Hwan | ko |
dc.contributor.author | Muralidharan, P. | ko |
dc.contributor.author | Kim, Do Kyung | ko |
dc.date.accessioned | 2010-12-08T09:21:50Z | - |
dc.date.available | 2010-12-08T09:21:50Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2009-12 | - |
dc.identifier.citation | ELECTROCHIMICA ACTA, v.54, no.28, pp.7495 - 7501 | - |
dc.identifier.issn | 0013-4686 | - |
dc.identifier.uri | http://hdl.handle.net/10203/20850 | - |
dc.description.abstract | Enhancement of oxide-ion conductivity has been investigated with emphasis on the high sintering temperature of apatite-type structure lanthanum silicate (La10Si6O27) as a potential electrolyte for intermediate-temperature solid oxide fuel cells (IT-SOFCs). The influence of the sintering temperatures 1500, 1550, 1600 and 1650 degrees C as a function of ionic conductivity of the La10Si6O27 electrolyte synthesized via a diethylamine (DEA) precipitation process has been characterized using impedance spectroscopy. The ionic conductivity of the La10Si6O27 electrolyte sintered at 1650 degrees C revealed a higher value(1.22 x 10(-2) S cm(-1) at 700 degrees C) of one order of magnitude than the pellets sintered at lower temperatures. The sintered La10Si6O27 pellets have been characterized by Si-29 NMR and Raman spectroscopy. The Si-29 NMR data showed the characteristic secondary peak at similar to 81.2 ppm, which confirmed the interstitial oxygen content contributing to high oxide-ion conduction. The Raman spectra revealed the appearance of a new resolved band centered at 861 cm(-1) for the pellet sintered at 1650 degrees C compared with lower temperatures sintered pellets. The results confirmed the possibility of local structural distortion to create additional pathways for interstitial oxide-ion conduction between channels leading to higher conductivity for the pellets sintered above 1600 degrees C. Thus, the conduction pathway may be determined by the co-operative displacements of the SiO4 substructure units formed at elevated sintering temperatures for high oxide-ion conductivity. (C) 2009 Elsevier Ltd. All rights reserved. | - |
dc.description.sponsorship | This work was financially supported by the Korea Research Foundation Grant funded by the Korean government (MOEHRD; KRF-2008-005-J00903). This work was also partially supported by Brain Korea 21 (BK21) program from Korean Ministry of Education. | en |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.subject | ELECTRICAL-PROPERTIES | - |
dc.subject | APATITE OXIDE | - |
dc.subject | FUEL-CELLS | - |
dc.subject | LA9.33SI6O26 | - |
dc.subject | TRANSPORT | - |
dc.subject | SPECTRA | - |
dc.subject | CONDUCTORS | - |
dc.subject | ROUTE | - |
dc.subject | GD | - |
dc.title | Raman and Si-29 NMR spectroscopic characterization of lanthanum silicate electrolytes: Emphasis on sintering temperature to enhance the oxide-ion conductivity | - |
dc.type | Article | - |
dc.identifier.wosid | 000271151600050 | - |
dc.identifier.scopusid | 2-s2.0-70349627657 | - |
dc.type.rims | ART | - |
dc.citation.volume | 54 | - |
dc.citation.issue | 28 | - |
dc.citation.beginningpage | 7495 | - |
dc.citation.endingpage | 7501 | - |
dc.citation.publicationname | ELECTROCHIMICA ACTA | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Kim, Do Kyung | - |
dc.contributor.nonIdAuthor | Muralidharan, P. | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Lanthanum silicate | - |
dc.subject.keywordAuthor | Apatite-structure | - |
dc.subject.keywordAuthor | DEA process | - |
dc.subject.keywordAuthor | Raman spectroscopy | - |
dc.subject.keywordAuthor | Solid state Si-29 NMR | - |
dc.subject.keywordAuthor | Sintering temperature | - |
dc.subject.keywordAuthor | Impedance | - |
dc.subject.keywordAuthor | SOFC | - |
dc.subject.keywordPlus | ELECTRICAL-PROPERTIES | - |
dc.subject.keywordPlus | APATITE OXIDE | - |
dc.subject.keywordPlus | FUEL-CELLS | - |
dc.subject.keywordPlus | LA9.33SI6O26 | - |
dc.subject.keywordPlus | TRANSPORT | - |
dc.subject.keywordPlus | SPECTRA | - |
dc.subject.keywordPlus | CONDUCTORS | - |
dc.subject.keywordPlus | ROUTE | - |
dc.subject.keywordPlus | GD | - |
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