DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kwak, Jaewoo | ko |
dc.contributor.author | Van Nghia, Nguyen | ko |
dc.contributor.author | Lee, Junseong | ko |
dc.contributor.author | Kim, Hyoseok | ko |
dc.contributor.author | Park, Myung Hwan | ko |
dc.contributor.author | Lee, Min Hyung | ko |
dc.date.accessioned | 2015-11-20T08:59:09Z | - |
dc.date.available | 2015-11-20T08:59:09Z | - |
dc.date.created | 2015-04-13 | - |
dc.date.created | 2015-04-13 | - |
dc.date.issued | 2015 | - |
dc.identifier.citation | DALTON TRANSACTIONS, v.44, no.10, pp.4765 - 4772 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.uri | http://hdl.handle.net/10203/200936 | - |
dc.description.abstract | A series of mono-, di-, and tri-phosphine oxide substituted triarylboranes, Mes(2)BAr (1), MesBAr(2) (2), and BAr3 (3) (Ar = 4-(Ph2PO)-2,6-Me-2-C6H2) were prepared to investigate the effect of a phosphine oxide group (Ph2PO) on Lewis acidity enhancement of triarylboranes. The X-ray crystal structure of 3 revealed peripheral decoration of Ph2PO groups with a C-3-axis perpendicular to the trigonal boron center. UV/Vis absorption and PL spectra indicated a significant contribution of pi(Mes or phenylene) -> p(pi)(B) charge transfer in the lower-energy electronic transition. The reduction potential measured by cyclic voltammetry showed apparent LUMO stabilization by introduction of phosphine oxide groups, the extent of which gradually increased with the increasing number of phosphine oxide groups. Lewis acidity enhancement was also supported by the gradual increase in fluoride ion affinity in the order 3 > 2 > 1. Theoretical calculations suggest that introduction of a Ph2PO group into a triarylborane significantly enhances the Lewis acidity of the boron center via an inductive electron-withdrawing effect and this effect is additive for multiple phosphine oxide groups. | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | LIGHT-EMITTING-DIODES | - |
dc.subject | AMORPHOUS MOLECULAR MATERIALS | - |
dc.subject | WEAKLY COORDINATING ANIONS | - |
dc.subject | STEREOSPECIFIC OLEFIN POLYMERIZATION | - |
dc.subject | ORGANIC ELECTROLUMINESCENT DEVICES | - |
dc.subject | 3-COORDINATE ORGANOBORON COMPOUNDS | - |
dc.subject | FLUORIDE SENSING PROPERTIES | - |
dc.subject | ELECTRON-ACCEPTING ABILITY | - |
dc.subject | DEEP-BLUE | - |
dc.subject | BINDING-PROPERTIES | - |
dc.title | Lewis acidity enhancement of triarylborane by appended phosphine oxide groups | - |
dc.type | Article | - |
dc.identifier.wosid | 000350543000044 | - |
dc.identifier.scopusid | 2-s2.0-84929377301 | - |
dc.type.rims | ART | - |
dc.citation.volume | 44 | - |
dc.citation.issue | 10 | - |
dc.citation.beginningpage | 4765 | - |
dc.citation.endingpage | 4772 | - |
dc.citation.publicationname | DALTON TRANSACTIONS | - |
dc.identifier.doi | 10.1039/c5dt00042d | - |
dc.contributor.nonIdAuthor | Kwak, Jaewoo | - |
dc.contributor.nonIdAuthor | Van Nghia, Nguyen | - |
dc.contributor.nonIdAuthor | Lee, Junseong | - |
dc.contributor.nonIdAuthor | Park, Myung Hwan | - |
dc.contributor.nonIdAuthor | Lee, Min Hyung | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | LIGHT-EMITTING-DIODES | - |
dc.subject.keywordPlus | AMORPHOUS MOLECULAR MATERIALS | - |
dc.subject.keywordPlus | WEAKLY COORDINATING ANIONS | - |
dc.subject.keywordPlus | STEREOSPECIFIC OLEFIN POLYMERIZATION | - |
dc.subject.keywordPlus | ORGANIC ELECTROLUMINESCENT DEVICES | - |
dc.subject.keywordPlus | 3-COORDINATE ORGANOBORON COMPOUNDS | - |
dc.subject.keywordPlus | FLUORIDE SENSING PROPERTIES | - |
dc.subject.keywordPlus | ELECTRON-ACCEPTING ABILITY | - |
dc.subject.keywordPlus | DEEP-BLUE | - |
dc.subject.keywordPlus | BINDING-PROPERTIES | - |
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