DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Songhyun | ko |
dc.contributor.author | Lee, Kyungho | ko |
dc.contributor.author | Im, Ju Hwan | ko |
dc.contributor.author | Kim, Hyung-Jun | ko |
dc.contributor.author | Choi, Min-Kee | ko |
dc.date.accessioned | 2015-06-03T06:19:41Z | - |
dc.date.available | 2015-06-03T06:19:41Z | - |
dc.date.created | 2015-05-26 | - |
dc.date.created | 2015-05-26 | - |
dc.date.created | 2015-05-26 | - |
dc.date.created | 2015-05-26 | - |
dc.date.issued | 2015-05 | - |
dc.identifier.citation | JOURNAL OF CATALYSIS, v.325, pp.26 - 34 | - |
dc.identifier.issn | 0021-9517 | - |
dc.identifier.uri | http://hdl.handle.net/10203/198692 | - |
dc.description.abstract | Historically, Pt/LTA (e.g., Pt/NaA) has often been used as a model catalyst for studying the catalytic functions of hydrogen spillover (H spillover). Notably, none of the works reported appreciable catalytic activities for Pt/LTA alone, while markedly enhanced activities were reported after physical dilution with some acidic oxides. It was often speculated without experimental evidence that activated hydrogen generated from Pt/LTA can migrate to the diluents surface ("inter-particular" H spillover) where organic reactants can react with spilt-over hydrogen. In this work, we carefully studied benzene hydrogenation activities of Pt/NaA and its decationized form (Pt/HA), before and after the physical dilution with various metal oxides possessing different Lewis and Bronsted acidity. The originally negligible activity of Pt/NaA increased significantly after mixing with various acidic oxides. The physical dilutions, however, resulted in a significant alteration of Pt/NaA structure due to solid-state H+ exchange, which made the catalytic interpretation vague. In contrast, Pt/HA structure did not change after the dilutions, and thus could be used as an ideal catalytic model system for studying inter-particular H spillover. The catalytic results showed that Al-rich metal oxides with abundant Lewis acid sites are effective for enhancing the catalytic activity. | - |
dc.language | English | - |
dc.publisher | ACADEMIC PRESS INC ELSEVIER SCIENCE | - |
dc.title | Revisiting hydrogen spillover in Pt/LTA: Effects of physical diluents having different acid site distributions | - |
dc.type | Article | - |
dc.identifier.wosid | 000353750400004 | - |
dc.identifier.scopusid | 2-s2.0-84941619895 | - |
dc.type.rims | ART | - |
dc.citation.volume | 325 | - |
dc.citation.beginningpage | 26 | - |
dc.citation.endingpage | 34 | - |
dc.citation.publicationname | JOURNAL OF CATALYSIS | - |
dc.identifier.doi | 10.1016/j.jcat.2015.02.018 | - |
dc.contributor.localauthor | Kim, Hyung-Jun | - |
dc.contributor.localauthor | Choi, Min-Kee | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Hydrogen spillover | - |
dc.subject.keywordAuthor | Physical dilution | - |
dc.subject.keywordAuthor | Lewis acid | - |
dc.subject.keywordAuthor | Catalytic enhancement | - |
dc.subject.keywordPlus | STATE ION-EXCHANGE | - |
dc.subject.keywordPlus | CATALYTIC CONSEQUENCES | - |
dc.subject.keywordPlus | SILICA-ALUMINA | - |
dc.subject.keywordPlus | ZEOLITES | - |
dc.subject.keywordPlus | TEMPERATURE | - |
dc.subject.keywordPlus | MIGRATION | - |
dc.subject.keywordPlus | STRENGTH | - |
dc.subject.keywordPlus | CARBONS | - |
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