Highly Stable Nanoporous Sulfur-Bridged Covalent Organic Polymers for Carbon Dioxide Removal

Cited 131 time in webofscience Cited 131 time in scopus
  • Hit : 689
  • Download : 0
DC FieldValueLanguage
dc.contributor.authorPatel, Hasmukh A.ko
dc.contributor.authorKaradas, Ferdiko
dc.contributor.authorByun, Jeehyeko
dc.contributor.authorPark, Joonhoko
dc.contributor.authorDeniz, Erhanko
dc.contributor.authorCanlier, Aliko
dc.contributor.authorJung, Yousungko
dc.contributor.authorAtilhan, Mertko
dc.contributor.authorYavuz, Cafer Tko
dc.date.accessioned2013-08-08T06:00:11Z-
dc.date.available2013-08-08T06:00:11Z-
dc.date.created2013-06-24-
dc.date.created2013-06-24-
dc.date.created2013-06-24-
dc.date.issued2013-05-
dc.identifier.citationADVANCED FUNCTIONAL MATERIALS, v.23, no.18, pp.2270 - 2276-
dc.identifier.issn1616-301X-
dc.identifier.urihttp://hdl.handle.net/10203/174729-
dc.description.abstractCarbon dioxide capture and separation requires robust solids that can stand harsh environments where a hot mixture of gases is often found. Herein, the first and comprehensive syntheses of porous sulfur-bridged covalent organic polymers (COPs) and their application for carbon dioxide capture in warm conditions and a wide range of pressures (0200 bar) are reported. These COPs can store up to 3294 mg g1 of carbon dioxide at 318 K and 200 bar while being highly stable against heating up to 400 degrees C. The carbon dioxide capacity of the COPs is also not hindered upon boiling in water for at least one week. Physisorptive binding is prevalent with isosteric heat of adsorptions around 24 kJ mol1. M062X and RIMP2 calculations yield the same relative trend of binding energies, where, interestingly, the dimer of triazine and benzene play a cooperative role for a stronger binding of CO2 (19.2 kJ mol1) as compared to a separate binding with triazine (13.3 kJ mol1) or benzene (11.8 kJ mol1).-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.titleHighly Stable Nanoporous Sulfur-Bridged Covalent Organic Polymers for Carbon Dioxide Removal-
dc.typeArticle-
dc.identifier.wosid000318502700009-
dc.identifier.scopusid2-s2.0-84877269348-
dc.type.rimsART-
dc.citation.volume23-
dc.citation.issue18-
dc.citation.beginningpage2270-
dc.citation.endingpage2276-
dc.citation.publicationnameADVANCED FUNCTIONAL MATERIALS-
dc.identifier.doi10.1002/adfm.201202442-
dc.contributor.localauthorPark, Joonho-
dc.contributor.localauthorJung, Yousung-
dc.contributor.localauthorYavuz, Cafer T-
dc.contributor.nonIdAuthorPatel, Hasmukh A.-
dc.contributor.nonIdAuthorKaradas, Ferdi-
dc.contributor.nonIdAuthorByun, Jeehye-
dc.contributor.nonIdAuthorDeniz, Erhan-
dc.contributor.nonIdAuthorCanlier, Ali-
dc.contributor.nonIdAuthorAtilhan, Mert-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorporous polymers-
dc.subject.keywordAuthorcarbon dioxide-
dc.subject.keywordAuthorthermal stability-
dc.subject.keywordAuthoradsorption-
dc.subject.keywordPlusCO2 CAPTURE-
dc.subject.keywordPlusINTRINSIC MICROPOROSITY-
dc.subject.keywordPlusGAS-STORAGE-
dc.subject.keywordPlusADSORPTION-
dc.subject.keywordPlusFRAMEWORKS-
dc.subject.keywordPlusCHEMISTRY-
dc.subject.keywordPlusTEMPLATE-
dc.subject.keywordPlusCAPACITY-
dc.subject.keywordPlusPOROSITY-
dc.subject.keywordPlusNITRIDE-
Appears in Collection
EEW-Journal Papers(저널논문)CBE-Journal Papers(저널논문)
Files in This Item
There are no files associated with this item.
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡ Click to see webofscience_button
⊙ Cited 131 items in WoS Click to see citing articles in records_button

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0