Herein we present an environmentally robust photopolymer system containing monomer stabilizer and thereby can improve the shelf-life stability of conventional photopolymer media. In this report, we conducted systematic study of the radical scavenger effect on shelf-life time in terms of achievable diffraction efficiency of photopolymers as a function of storage time. Furthermore, the stability of photopolymerizable monomer was also discussed regarding to monomer conversion by FT-Raman analysis during the storage. (c) 2012 Elsevier B.V. All rights reserved.