Microstructural Properties and Formation Mechanisms of Zn Nanocrystal Embedded Polydimethylsiloxane Nanofibers

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The silicone-sheathed nanofibers based on ZnO-SiOx nanofibers transformed into Zn nanocrystal embedded polydimethylsiloxane (silicone) nanofibers by using electron-beam irradiation. Transmission electron microscopy (TEM) images showed that silicone-sheathed ZnO-SiOx nanofibers were synthesized during electron-beam irradiation of the calcined ZnO-SiOx nanofiber. High-resolution TEM image showed that the nanofibers were transformed into Zn nanocrystal embedded silicone nanofibers. The structural variation of the nanofibers was attributed to the evaporation and deposition of the silicone molecule and to the thermodynamic and double ionization effects during electron beam irradiation. The Zn nanocrystal embedded silicone nanofibers were formed due to the oxidation and the reduction due to the thermal and double ionization effects at the later stage of the electron-beam irradiation. (C) 2012 The Electrochemical Society. [DOI: 10.1149/2.050205jes]
Publisher
ELECTROCHEMICAL SOC INC
Issue Date
2012-02
Language
English
Article Type
Article
Keywords

CORE-SHELL; SOLAR-CELLS; NANOWIRES; ZNS/SIO2; SIO2; SILICA; ARRAYS

Citation

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, v.159, no.5, pp.122 - 126

ISSN
0013-4651
DOI
10.1149/2.050205jes
URI
http://hdl.handle.net/10203/104119
Appears in Collection
MS-Journal Papers(저널논문)
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