DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shanbhag, GV | ko |
dc.contributor.author | Choi, MinKee | ko |
dc.contributor.author | Kim, J | ko |
dc.contributor.author | Ryoo, Ryong | ko |
dc.date.accessioned | 2009-07-14T02:10:40Z | - |
dc.date.available | 2009-07-14T02:10:40Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2009-05 | - |
dc.identifier.citation | JOURNAL OF CATALYSIS, v.264, no.1, pp.88 - 92 | - |
dc.identifier.issn | 0021-9517 | - |
dc.identifier.uri | http://hdl.handle.net/10203/10038 | - |
dc.description.abstract | Mesoporous socialite with a mesoporous/microporous hierarchical structure was successfully synthesized using an organosilane surfactant. It showed about 10-fold high surface area and 4-fold large pore volume, as compared with sodalite with solely microporous structure. The basicity of MPSOD was higher than that of CsNaX or KAIMCM-41. The catalytic activities of this mesoporous zeolite were evaluated for various base catalyzed reactions involving bulky and small substrates, viz. Knoevenagel condensation, Claisen-Schmidt condensation in liquid phase, and acetonylacetone cyclization in vapor phase. The catalyst showed higher activity and longer lifetime than CsNaX and KAIMCM-41. (C) 2009 Elsevier Inc. All rights reserved. | - |
dc.description.sponsorship | This work was supported by National Honor Scientist Program of the Ministry of Education, Science and Technology in Korea. | en |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | ACADEMIC PRESS INC ELSEVIER SCIENCE | - |
dc.subject | MCM-41 | - |
dc.subject | ZEOLITES | - |
dc.title | Mesoporous sodalite: A novel, stable solid catalyst for base-catalyzed organic transformations | - |
dc.type | Article | - |
dc.identifier.wosid | 000266734100009 | - |
dc.identifier.scopusid | 2-s2.0-67349164025 | - |
dc.type.rims | ART | - |
dc.citation.volume | 264 | - |
dc.citation.issue | 1 | - |
dc.citation.beginningpage | 88 | - |
dc.citation.endingpage | 92 | - |
dc.citation.publicationname | JOURNAL OF CATALYSIS | - |
dc.identifier.doi | 10.1016/j.jcat.2009.03.014 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Choi, MinKee | - |
dc.contributor.localauthor | Ryoo, Ryong | - |
dc.contributor.nonIdAuthor | Shanbhag, GV | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Mesoporous zeolite | - |
dc.subject.keywordAuthor | Hierarchical | - |
dc.subject.keywordAuthor | Sodalite | - |
dc.subject.keywordAuthor | Basicity | - |
dc.subject.keywordAuthor | Solid base | - |
dc.subject.keywordAuthor | Knoevenagel | - |
dc.subject.keywordAuthor | Claisen-Schmidt | - |
dc.subject.keywordAuthor | Catalyst deactivation | - |
dc.subject.keywordPlus | MCM-41 | - |
dc.subject.keywordPlus | ZEOLITES | - |
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