DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Da-Jung | ko |
dc.contributor.author | Hong, Youn-Jin | ko |
dc.contributor.author | Kim, So-Han | ko |
dc.contributor.author | Lee, Kang-Mun | ko |
dc.contributor.author | Mun, Sang-deok | ko |
dc.contributor.author | Yoon, Sung-Woo | ko |
dc.contributor.author | Lee, Jun-Seong | ko |
dc.contributor.author | Do, Young-Kyu | ko |
dc.contributor.author | Kim, Young-Jo | ko |
dc.date.accessioned | 2013-03-11T01:42:17Z | - |
dc.date.available | 2013-03-11T01:42:17Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2011-11 | - |
dc.identifier.citation | INORGANICA CHIMICA ACTA, v.378, no.1, pp.311 - 314 | - |
dc.identifier.issn | 0020-1693 | - |
dc.identifier.uri | http://hdl.handle.net/10203/97949 | - |
dc.description.abstract | New types of boratranes B[(O-o-ArCH(2))(3-) (n)N(CH(2)CH(2)O)(n)] (Ar = 2,4-di-MeC(6)H(2); n = 0, 1; n = 1, 2; n = 2, 3) featuring three six-membered chelating ring (1) to two five-membered chelating rings (3) in a stepwise fashion through 2 have been synthesized by the reaction of B(OMe)(3) with a series of tetradentate ligands such as (HO-o-ArCH(2))(3-) (n)N(CH(2)CHOH)(n) (Ar = 2,4-di-MeC(6)H(2); n = 0, L1H(3); n = 1, L2H(3); n = 2, L3H(3)). Compounds 1-3 have been characterized by solution (1)H, (13)C{(1)H} and, (11)B NMR and the crystal structures of 1 and 3 have been determined by single crystal X-ray diffraction. Compounds 1 and 3 are the first structurally characterized boratrane derivatives bearing all six-membered rings and mixed ring systems in the atrane cage, respectively. Especially, the molecular structures of 1 revealed that its transannular N-B bond length of 1.6322(19) angstrom is the shortest among the previously reported boratrane and its derivatives. (C) 2011 Elsevier B.V. All rights reserved. | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.subject | DYNAMIC NMR BEHAVIOR | - |
dc.subject | ETHYLENE POLYMERIZATION | - |
dc.subject | TRIPTYCH-BOROXAZOLIDINES | - |
dc.subject | TITANIUM(IV) COMPLEXES | - |
dc.subject | MOLECULAR-STRUCTURE | - |
dc.subject | LIGANDS | - |
dc.subject | SUBSTITUENTS | - |
dc.subject | TITANATRANES | - |
dc.subject | PHOSPHORUS | - |
dc.subject | SILATRANES | - |
dc.title | Boratranes with all six-membered rings or with two different ring sizes: Synthesis, characterization, and X-ray crystal structures | - |
dc.type | Article | - |
dc.identifier.wosid | 000296538000045 | - |
dc.identifier.scopusid | 2-s2.0-80054985216 | - |
dc.type.rims | ART | - |
dc.citation.volume | 378 | - |
dc.citation.issue | 1 | - |
dc.citation.beginningpage | 311 | - |
dc.citation.endingpage | 314 | - |
dc.citation.publicationname | INORGANICA CHIMICA ACTA | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Do, Young-Kyu | - |
dc.contributor.nonIdAuthor | Kim, Da-Jung | - |
dc.contributor.nonIdAuthor | Hong, Youn-Jin | - |
dc.contributor.nonIdAuthor | Kim, So-Han | - |
dc.contributor.nonIdAuthor | Mun, Sang-deok | - |
dc.contributor.nonIdAuthor | Yoon, Sung-Woo | - |
dc.contributor.nonIdAuthor | Lee, Jun-Seong | - |
dc.contributor.nonIdAuthor | Kim, Young-Jo | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Boratrane | - |
dc.subject.keywordAuthor | (2-Hydroxy-3,5-dimethylbenzyl)diethanolamine | - |
dc.subject.keywordAuthor | Bis(2-hydroxy-3,5-dimethylbenzyl)ethanolamine | - |
dc.subject.keywordAuthor | Tris(2-hydroxy-3,5-dimethylbenzyl)amine | - |
dc.subject.keywordAuthor | X-ray crystal structure | - |
dc.subject.keywordPlus | DYNAMIC NMR BEHAVIOR | - |
dc.subject.keywordPlus | ETHYLENE POLYMERIZATION | - |
dc.subject.keywordPlus | TRIPTYCH-BOROXAZOLIDINES | - |
dc.subject.keywordPlus | TITANIUM(IV) COMPLEXES | - |
dc.subject.keywordPlus | MOLECULAR-STRUCTURE | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | SUBSTITUENTS | - |
dc.subject.keywordPlus | TITANATRANES | - |
dc.subject.keywordPlus | PHOSPHORUS | - |
dc.subject.keywordPlus | SILATRANES | - |
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