Thioether S-ligation in a side-on mu-eta(2):eta(2)-peroxodicopper(II) complex
[(ANS)Cu-I(CH3CN)](+) reacts with O-2 giving [{(ANS)Cu-II}(2)(mu-eta(2):eta(2)-O-2(2-))](2+), nu(O-O) = 731 cm(-1), shown to possess S-thioether ligation, based on comparisons with analogues having all N-ligands or a -S(Ph) group. The finding is a rare occurrence and new for side-on O-2(2-) binding.
- Publisher
- ROYAL SOC CHEMISTRY
- Issue Date
- 2010-01
- Language
- English
- Article Type
- Article
- Keywords
ALPHA-HYDROXYLATING MONOOXYGENASE; INCLUDING SULFUR-LIGATION; COPPER-DIOXYGEN CHEMISTRY; CATALYTIC MECHANISM; MONONUCLEAR COPPER; BETA-MONOOXYGENASE; END-ON; REACTIVITY; LIGAND; DOPAMINE
- Citation
CHEMICAL COMMUNICATIONS, v.46, no.1, pp.91 - 93
- ISSN
- 1359-7345
- Appears in Collection
- CH-Journal Papers(저널논문)
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