Synthesis and Properties of Diblock Copolymers Containing Poly(3-Hexylthiophene) and Poly(Fluorooctyl Methacrylate)

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This study reports the synthesis of regioregular poly(3-hexylthiophene)-b-poly(1H,1H-dihydro perfluorooctyl methacrylate) (P3HT-b-PFOMA) block copolymers by atom transfer radical polymerization of FOMA using P3HT macroinitiators. The P3HT macroinitiator was previously prepared by chemical modification of hydroxy terminated P3HT. The block copolymers were characterized by (1)H-NMR, (13)C-NMR, GPC, DSC, TGA and TEM. The block copolymers are able to self-assemble into phase separated micellar thin film morphology from chloroform.
Publisher
AMER SCIENTIFIC PUBLISHERS
Issue Date
2011-02
Language
English
Article Type
Article; Proceedings Paper
Citation

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, v.11, no.2, pp.1696 - 1700

ISSN
1533-4880
DOI
10.1166/jnn.2011.3330
URI
http://hdl.handle.net/10203/96724
Appears in Collection
NT-Journal Papers(저널논문)CH-Journal Papers(저널논문)
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